Influence of temperature on the electrosorption of ions from aqueous solutions using mesoporous carbon materials

2013 ◽  
Vol 116 ◽  
pp. 206-213 ◽  
Author(s):  
K. Sharma ◽  
R.T. Mayes ◽  
J.O. Kiggans Jr. ◽  
S. Yiacoumi ◽  
J. Gabitto ◽  
...  
2020 ◽  
Vol 190 ◽  
pp. 294-311
Author(s):  
Katarzyna Jedynak ◽  
Marta Repelewicz ◽  
Krystyna Kurdziel ◽  
Dariusz Wideł

Author(s):  
Yiqun Huang ◽  
Pawan Singh Takhar ◽  
Juming Tang ◽  
Barry G Swanson

Rheological behaviors of high acyl (HA) gellan are not well understood partially because of its relatively late commercialization compared to low acyl gellan. The objective of this study was to investigate the effect of temperature (5-30 °C), calcium (0, 1 and 10 mM) and gellan concentrations (0.0044-0.1000% w/v) on the flow behaviors of high acyl gellan aqueous solutions using rheological tests. Gellan solutions with 0 or 1 mM added Ca++ exhibited shear thinning behavior at gellan concentrations above 0.0125%. The influence of temperature on apparent viscosity (shear rate, 100 s-1) of gellan solutions can be described with an Arrhenius relationship. The apparent viscosity of gellan solution at low concentrations was more sensitive to temperature changes. The addition of Ca++ led to a decrease in flow resistance for a dilute gellan solution (<0.0125%), but an increased resistance for a relatively concentrated gellan solution (>0.0125%).


Attention has previously been directed by one of us to the existence of a differential septum enclosing the seeds of Hordeum (barley). When the seeds are immersed in aqueous solutions of most electrolytes, and of many non-electrolytes, this covering behaves as a very efficient differential septum, water alone entering the seeds under the attractive influence of the finely granulated contents. The rate at which the water enters is considerably affected if substances are dissolved in it, being increased by some and diminished by others; it is also markedly dependent on the temperature of the water or solution in which the seeds are immersed. Variations of the rate at which water enters with alterations of the experimental conditions are presumably due mainly to changes in the water, and the seeds of Hordeum would thus appear to be a very suitable medium for the investigation of the nature of the changes produced in water by the presence of dissolved substances or by alterations of temperature.


2021 ◽  
pp. 139132
Author(s):  
Madis Lüsi ◽  
Heiki Erikson ◽  
Kaido Tammeveski ◽  
Alexey Treshchalov ◽  
Arvo Kikas ◽  
...  

2013 ◽  
Vol 52 (43) ◽  
pp. 15187-15197 ◽  
Author(s):  
Michaël Carboni ◽  
Carter W. Abney ◽  
Kathryn M. L. Taylor-Pashow ◽  
Juan L. Vivero-Escoto ◽  
Wenbin Lin

2012 ◽  
Vol 554-556 ◽  
pp. 778-782 ◽  
Author(s):  
Chao Liu ◽  
Yong Qi Hu ◽  
Yi Feng Yu ◽  
Yue Zhang ◽  
Yan Yan Wang ◽  
...  

Nitrogen-doped mesoporous carbon materials have been synthesized by using melamine-formaldehyde resin as carbon precursor and SBA-15 as a removable template. The structure of the materials was investigated by X-ray diffraction, BET specific surface area analysis, Fourier transform infrared spectroscopy, and thermogravimetric analysis. X-ray and BET studies confirmed that a pore nanostructure is inherited from the silica templates. Fourier transform infrared spectroscopy analysis showed N atoms are strongly bonded in the carbon structure in heterocycles or nitrile functions. These mesoporous nitrogen-doped carbon materials exhibits textural properties with BET surface areas ranging between 400 and 600 m2/g and uniform pore size(3.9 nm). The mechanism of carbonization process is studied by thermogravimetric analysis. The ratio of melamine/formaldehyde plays an important role during the carbonization process for the surface areas and textural properties, and element analysis reveals that the nitrogen content of the mesoporous carbon materials is as high as 10wt%.


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