Four Rhodamine B-based fluorescent chemosensor for Fe3+ in aqueous solution

2012 ◽  
Vol 174 ◽  
pp. 231-236 ◽  
Author(s):  
Meimei Chai ◽  
Di Zhang ◽  
Min Wang ◽  
Huijie Hong ◽  
Yong Ye ◽  
...  
Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3598
Author(s):  
Nirmal K. Shee ◽  
Hee-Joon Kim

A series of porphyrin triads (1–6), based on the reaction of trans-dihydroxo-[5,15-bis(3-pyridyl)-10,20-bis(phenyl)porphyrinato]tin(IV) (SnP) with six different phenoxy Zn(II)-porphyrins (ZnLn), was synthesized. The cooperative metal–ligand coordination of 3-pyridyl nitrogens in the SnP with the phenoxy Zn(II)-porphyrins, followed by the self-assembly process, leads to the formation of nanostructures. The red-shifts and remarkable broadening of the absorption bands in the UV–vis spectra for the triads in CHCl3 indicate that nanoaggregates may be produced in the self-assembly process of these triads. The emission intensities of the triads were also significantly reduced due to the aggregation. Microscopic analyses of the nanostructures of the triads reveal differences due to the different substituents on the axial Zn(II)-porphyrin moieties. All these nanomaterials exhibited efficient photocatalytic performances in the degradation of rhodamine B (RhB) dye under visible light irradiation, and the degradation efficiencies of RhB in aqueous solution were observed to be 72~95% within 4 h. In addition, the efficiency of the catalyst was not impaired, showing excellent recyclability even after being applied for the degradation of RhB in up to five cycles.


Heliyon ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. e06851
Author(s):  
Usha Jinendra ◽  
Dinesh Bilehal ◽  
B.M. Nagabhushana ◽  
Avvaru Praveen Kumar

2014 ◽  
Vol 513-517 ◽  
pp. 65-69
Author(s):  
Xiao Jun Hu ◽  
Xin Yan Hu ◽  
Zhi Zhang

According to the principle of dynamic quenching a new ON-OFF fluorescent chemosensor for Cu2+ions was designed, this chemosensor was composed of p-tert-butylthiacalix [arene (TCA),sodium dodecyl sulfate (SDS) and perylene through the form of self-assembly in aqueous solution. Addition of Cu2+ions could result in a quenching of the fluorescence emission of perylene inside micelles, which due to intramicellar complex-fluorophore electron-transfer or energy-transfer effects induced by the complexation of TCA with the Cu2+ions.The experimental results indicated that: Under the condition of TCA/perylene was 800/1, SDS concentration was 150mmol/L and pH value above 9, according to the fluorescence quenching ,within a certain range of the concentration of Cu2+ion can be linearly determined.


2014 ◽  
Vol 21 (14) ◽  
pp. 8585-8594 ◽  
Author(s):  
Puthiya Veetil Nidheesh ◽  
Rajan Gandhimathi
Keyword(s):  

Desalination ◽  
2008 ◽  
Vol 230 (1-3) ◽  
pp. 16-26 ◽  
Author(s):  
N. Daneshvar ◽  
M.A. Behnajady ◽  
M. Khayyat Ali Mohammadi ◽  
M.S. Seyed Dorraji

RSC Advances ◽  
2014 ◽  
Vol 4 (110) ◽  
pp. 64747-64755 ◽  
Author(s):  
Xuefeng Xu ◽  
Man Wang ◽  
Yanyan Pei ◽  
Changchun Ai ◽  
Liangjie Yuan

The micro/nano-structure composite SiO2@Ag/AgCl was employed as a low cost photocatalyst for the degradation of RhB in aqueous solution under visible light irradiation, which exhibited excellent photocatalytic performance and stability.


2013 ◽  
Vol 295-298 ◽  
pp. 475-478 ◽  
Author(s):  
Zhi Xiang Han ◽  
Ming Hui Du ◽  
Guo Xi Liang ◽  
Xiang Yang Wu

Rhodamine B thiohydrazide (RBS) was firstly employed as turn-on fluorescent probe for hypochlorite in aqueous solution and living cells. It exhibits a stable response to hypochlorite from 1.0×10-6to 1.0×10-5M with a detection limit of 3.3×10-7M. The response of this probe to hypochlorite is fast and highly selective compared with other reactive oxygen species (such as.OH,1O2, H2O2) and other common anions (such as X-, ClO2-, ClO4-, NO3-, NO2-, OH-, Ac-, CO32-, SO42-).


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