Enhancing visible-light activity of the self-cleaning TiO2-coated cotton fabrics by loading AgI particles

2011 ◽  
Vol 206 (6) ◽  
pp. 1175-1179 ◽  
Author(s):  
Deyong Wu ◽  
Mingce Long
2013 ◽  
Vol 634-638 ◽  
pp. 960-964
Author(s):  
De Yong Wu ◽  
Lian Zhi Wang

Self-cleaning fabrics have been successfully prepared by depositing and grafting TiO2 nanoparticles, and silane coupling agent 3-Aminopropyltriethoxysilane was adopted to improve the photocatalytic activity of self-cleaning fabrics. TEM results showed that the treatment of silane coupling agent is good for increasing the amount of TiO2 particles. The excellent photocatalytic activity of TiO2-coated cotton fabrics is attributed the increase of TiO2 particles and the formation of the TiO2/SiO2 structure.


Cellulose ◽  
2020 ◽  
Vol 27 (11) ◽  
pp. 6383-6398 ◽  
Author(s):  
Xinmei Guan ◽  
Yifei Zhan ◽  
Lin Yang ◽  
Jianwu Lan ◽  
Jiaojiao Shang ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7002
Author(s):  
Jiayi Chen ◽  
Kuang Wang ◽  
Jialong Tian ◽  
Wenhui Yu ◽  
Yujie Chen ◽  
...  

In this work, a visible-light-driven BiOCl/Bi2WO6 photocatalyst was obtained via a facile hydrothermal method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), X-ray photoelectron spectroscopy (XPS), ultraviolet/visible light diffuse reflection spectroscopy (UV/Vis), and photocurrent (PC). BiOCl/Bi2WO6 was modified with (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride to obtain the cationized BiOCl/Bi2WO6. Cotton fabric was pretreated with sodium hydroxide (NaOH) and sodium chloroacetate solution to obtain carboxymethylated cotton fabric, which was further reacted with cationized BiOCl/Bi2WO6 to achieve finished cotton fabric. The cotton fabrics were characterized by Fourier-transform infrared spectroscopy (FT-IR), XRD, SEM, and EDS. The photocatalytic activity of the BiOCl/Bi2WO6 photocatalyst and cotton fabrics was assessed by photocatalytic degradation of MB (methylene blue) solution under simulated visible light. The self-cleaning property of cotton fabrics was evaluated by removing MB solution and red-wine stains. Results revealed that the coated cotton fabrics exhibited appreciable photocatalytic and self-cleaning performance. In addition, anti-UV studies showed that the finished cotton fabrics had remarkable UV blocking properties in the UVA and UVB regions. Therefore, the finished cotton fabric with BiOCl/Bi2WO6 can provide a framework for the development of multifunctional textiles.


2021 ◽  
pp. 004051752110265
Author(s):  
Wenjun Li ◽  
Hui Zhang ◽  
Tianyu Chen ◽  
Limeng Yang ◽  
Cuihong Sheng ◽  
...  

The self-cleaning textiles coated with reduced graphene oxide-titanium dioxide (TiO2) nanocomposites have enhanced photocatalytic activities and could have great potential in practical applications. However, it is still problematic regarding how to avoid aggregation of reduced graphene oxide nanosheets in producing reduced graphene oxide-TiO2 nanocomposites. In this research article, we propose a new method to reduce the aggregation of reduced graphene oxide nanosheets in producing cotton fabrics coated with reduced graphene oxide-TiO2 nanocomposites by combining vibration-assisted ball milling and hydrothermal synthesis process. The microstructure and photocatalytic-related properties of the resultant reduced graphene oxide-TiO2 nanocomposites and their coating cotton fabrics were characterized by using a series of techniques including field emission scanning electron microscope (FESEM), atomic force microscope (AFM), X-ray diffraction spectroscopy (XRD), Raman, particle size distribution, Brunauer-Emmett-Teller,(BET), transmission electron microscope (TEM), X-ray photoelectron spectrometer (XPS), diffuse reflectance spectra (DRS), ultraviolet photoelectron spectroscope (UPS), and photoluminescence (PL). It was indicated that the aggregation of reduced graphene oxide nanosheets in reduced graphene oxide-TiO2 nanocomposites was successfully avoided via ball milling in the presence of tetrabutyl titanate. After hydrothermal treatment, the resulting reduced graphene oxide-TiO2 nanocomposites were firmly immobilized on cotton fabric. It was demonstrated in the self-cleaning experiments that the resultant self-cleaning cotton fabrics are hydrophilic and could directly decompose color contaminants such as methylene blue, Congo red, and coffee stains under simulated sunlight irradiation due to the photo-degradation reactions of the reduced graphene oxide-TiO2 nanocomposite coating. The reduced graphene oxide-TiO2 nanocomposite-modified cotton fabric also exhibited excellent performance in both robust abrasion resistance and soap-washing resistance. The fabric photocatalytic self-cleaning capability was not found to decrease significantly after being repeatedly used for five times.


2021 ◽  
Author(s):  
Ubong Eduok

Zirconia/polydimethylsiloxane nanocomposite coated fabric demonstrates unique stability with tendencies toward self-cleaning and oil–water separations due to its nanopatterned morphologies and adhering superhydrophobic polysiloxane chemical groups.


Cellulose ◽  
2019 ◽  
Vol 26 (4) ◽  
pp. 2821-2832 ◽  
Author(s):  
Ishaq Ahmad ◽  
Chi-wai Kan ◽  
Zhongping Yao

2014 ◽  
Vol 1033-1034 ◽  
pp. 1227-1234 ◽  
Author(s):  
Penwisa Pisitsak ◽  
Anchalee Porntrirat ◽  
Nisa Boonwang ◽  
Rabchok Thongcharoen ◽  
Nattaya Punrattanasin

In the textile industry, binders are used in fabric finishing processes to promote adhesion between a fiber surface and the particles of desired properties. In this research, a commercial polyurethane binder, Evo®Fin PUS, was used to attach photocatalytic TiO2nanoparticles (Degussa®, P-25) onto a cotton surface, in order to impart self-cleaning properties and to improve wash fastness. The cotton fabrics were finished with the aqueous dispersion of TiO2and the binder, consisting of 2, 4, and 6 % w/v for each component. Finishing was done via a pad-dry-cure process. Then a direct dye (C.I. Direct Blue 199), which was used as a model stain, was dropped onto each sample prior to 24-h illumination with simulated solar light. The self-cleaning properties were triggered by light and evaluated in terms of the reduction in color strength values (K/S) of the stain after exposure. The self-cleaning performance was preserved when the binder was added to the TiO2coating. However, washing reduced the self-cleaning performance of all samples because of the detachment of some TiO2particles, as observed by scanning electron microscopy. Overall, improved wash fastness was observed with the help of binder. Samples were further analyzed for mechanical properties, crease recovery, and drapeability.


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