Thermal degradation behavior of hydrogenated nitrile-butadiene rubber (HNBR)/clay nanocomposite and HNBR/clay/carbon nanotubes nanocomposites

2009 ◽  
Vol 491 (1-2) ◽  
pp. 103-108 ◽  
Author(s):  
Shuguo Chen ◽  
Haiyang Yu ◽  
Wentan Ren ◽  
Yong Zhang
Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3332
Author(s):  
Xiaohui Bao ◽  
Fangyi Wu ◽  
Jiangbo Wang

Via the surface-grafting of carbon nanotubes (CNTs) with a silicon-containing flame retardant (PMDA), a novel flame retardant CNTs-PMDA was synthesized. The flame retardancy was tested by cone calorimeter. Compared with pure epoxy resin, the total heat release (THR) and peak heat release rate (PHRR) of epoxy resin containing CNTs-PMDA were significantly reduced, by 44.6% and 24.6%, respectively. Furthermore, thermal degradation behavior of epoxy resin based composite was studied by the thermogravimetric analysis with differences in heating rates. The kinetic parameters of the thermal degradation for epoxy resin composites were evaluated by the Kissinger method and Flynn-Wall-Ozawa method. The results suggested that activation energy values of epoxy resin containing CNTs-PMDA in thermal degradation process were higher than those of pure epoxy resin in the final stage of the thermal degradation process, which was closely related to the final formation of char layer residues. Finally, the results from Dynamic mechanical thermal analysis (DMTA) and Scanning electron microscopy (SEM) measurements exhibited that the functionalization of CNTs with PMDA obviously improved the dispersion of CNTs in the epoxy resin matrix.


1999 ◽  
Vol 66 (3) ◽  
pp. 307-315 ◽  
Author(s):  
Pin-Sheng Wang ◽  
Wen-Yen Chiu ◽  
Leo-Wang Chen ◽  
Bar-Long Denq ◽  
Trong-Ming Don ◽  
...  

2016 ◽  
Vol 639 ◽  
pp. 84-90 ◽  
Author(s):  
Qifeng Chang ◽  
Lijuan Long ◽  
Wentao He ◽  
Shuhao Qin ◽  
Jie Yu

2015 ◽  
Vol 17 (3) ◽  
pp. 47-51 ◽  
Author(s):  
Syed H. Javed ◽  
Umair Aslam ◽  
Mohsin Kazmi ◽  
Masooma Rustam ◽  
Sheema Riaz ◽  
...  

Abstract Various siliceous agriculture waste (SAW) such as rice husk, wheat husk and bagasse have been investigated to study their thermal degradation behavior using Thermogravimetric Analyzer (TGA) technique. The focus of this research is to conduct TGA of raw and acid treated (20% HCl & 1M H2SO4) SAW at heating rate 10°C/min in the atmosphere of nitrogen. The results were analyzed on the basis of thermograms and it was inferred that 24 hours soaking with 20% HCl prior to thermal degradation enhanced the percent weight loss. The process also improved the percentage of residual weight of SAW indicating the extraction of amorphous silica with increased purity. The effect of acid treatment was verified by determining chemical composition of SAW samples before and after soaking with 20% HCl. Proximate analysis, thermal degradation temperature ranges and percentage of residual weight at 800°C for each of rice husk, wheat husk and bagasse were also quantified to observe the thermal degradation behavior. XRF analysis was performed to observe the effect of acid treatment for extraction of pure silica.


Sign in / Sign up

Export Citation Format

Share Document