Estimation and interpretation of infinite dilution solute–solvent interaction enthalpies in non-electrolyte aqueous solutions

2009 ◽  
Vol 496 (1-2) ◽  
pp. 66-70 ◽  
Author(s):  
Michael I. Davis ◽  
Gérard Douhéret ◽  
João Carlos R. Reis
Keyword(s):  
Aqueous Solutions ◽  
Infinite Dilution ◽  
Solvent Interaction ◽  
Solute Solvent Interaction

scholarly journals Molecular Interaction of Aqueous Solution of 1-Propanol and 2-Propanol

2019 ◽  
Vol 35 (2) ◽  
pp. 901-904
Author(s):  
Sandhya Sharma ◽  
N. D. Kandpal ◽  
R. Joshi
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Molecular Interaction ◽  
Aqueous Systems ◽  
Solvent Interaction ◽  
Solvent Type ◽  
Type Interaction ◽  
Alcohol System ◽  
Solute Solvent Interaction ◽  
Water Alcohol

Viscosities (ƞ) of solutions of 1- propanol and 2-propanol have been determined in aqueous systems of varying composition (0.16-3.64 mol dm-3) at 298 K. The ƞ/ƞ0 data have been analyzed in the light of reduced Jone-Dole equation ƞ/ƞ0 = BC+1. The results in the regards to solute-solvent interaction in aqueous solutions of both the alcohols have been discussed in the terms of the value B. The result of study reveals that both the alcohols behave as the structure makers in the water. The result shows that solute-solvent type interaction of same magnitude exists in water-alcohol system.

Studies on thermodynamics of solution by gas chromatography: solubility measurements of hydrocarbons in cycloalkanols

1977 ◽  
Vol 55 (7) ◽  
pp. 1273-1278 ◽  
Author(s):  
Rakesh K. Kuchhal ◽  
Kanai L. Mallik ◽  
Pyare L. Gupta
Keyword(s):  
Gas Chromatography ◽  
Liquid Chromatography ◽  
Activity Coefficient ◽  
Benzyl Alcohol ◽  
Infinite Dilution ◽  
Gas Liquid Chromatography ◽  
Liquid Equilibrium ◽  
Solvent Interaction ◽  
Solute Solvent Interaction ◽  
Statistical Approaches

Activity coefficients at infinite dilution have been determined by gas–liquid chromatography for nine hydrocarbons solutes in cyclopentanol, cyclohexanol, cycloheptanol, benzyl alcohol, and n-heptanol at 25 °C. Experimental results for cyclopentane and cyclohexane in cycloalkanols compare favourably with the values obtained by extrapolation to infinite dilution of activity coefficient data calculated from Benson et al.'s static (vapour–liquid equilibrium) measurements. Some characteristics of the solute–solvent interaction in the systems are discussed in light of statistical approaches (thermal and athermal contributions).

scholarly journals Studies on the Solute Solvent Interaction of Nimesulide in Aqueous Solutions of Hydrotropic Agents at Different Temperatures

2010 ◽  
Vol 7 (s1) ◽  
pp. S223-S230 ◽  
Author(s):  
Chandravir S. Solanki ◽  
Sushree Tripathy ◽  
Minaketan Tripathy ◽  
Upendra N. Dash
Keyword(s):  
Aqueous Solutions ◽  
Sodium Salicylate ◽  
Relative Viscosity ◽  
Partial Molar Volumes ◽  
Transition Theory ◽  
Solvent Interaction ◽  
Solvent Water ◽  
Different Temperatures ◽  
Density Values ◽  
Solute Solvent Interaction

The present study deals with experiments so as to highlight the solute (drug nimesulide) - solvent(water) interactions and related modifications in case of the presence of hydrotropic agents at different temperatures T(=298.15 to 313.15)K. Density and viscosity values of nimesulide have been determined in water in (0.1, 0.2, 0.4, 0.6, 0.8, 1 and 2) mol dm-3aqueous solutions of hydrotropic agents (sodium benzoate, sodium salicylate, sodium bromide and nicotinamide) at temperatures 298.15, 303.15, 308.15 and 313.15 K where as the solubility was studied at 308.15 K. From the density values, the limiting partial molar volumes and expansibilities have been calculated. The experimental viscosity values have been analyzed in terms of jones-dole equation and on the basis of transition theory for relative viscosity.

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