H-phosphinates, H-phosphonates and secondary phosphine oxides in radical reactions and strategy analysis

2021 ◽  
pp. 153352
Author(s):  
Zhan-Yong Wang ◽  
Qi Guo ◽  
Kai-Kai Wang ◽  
Shaohong Xu
Keyword(s):  
Radical Reactions ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Strategy Analysis

Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones

2016 ◽  
Vol 191 (11-12) ◽  
pp. 1480-1481 ◽  
Author(s):  
E. V. Gorbachuk ◽  
E. K. Badeeva ◽  
S. A. Katsyuba ◽  
P. O. Pavlov ◽  
Kh. R. Khayarov ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Phosphine Oxide ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Thermal Stability Of

Preparation of Optically Pure Tertiary Phosphine Oxides via the Addition ofP-Stereogenic Secondary Phosphine Oxide to Activated Alkenes

2016 ◽  
Vol 81 (17) ◽  
pp. 7644-7653 ◽  
Author(s):  
Ji-Ping Wang ◽  
Shao-Zhen Nie ◽  
Zhong-Yang Zhou ◽  
Jing-Jing Ye ◽  
Jing-Hong Wen ◽  
...  
Keyword(s):  
Phosphine Oxide ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Tertiary Phosphine ◽  
Optically Pure

Catalyst- and Solvent-Free Hydrophosphorylation of Ketones with Secondary Phosphine Oxides: Green Synthesis of Tertiary α-Hydroxyphosphine Oxides

Synthesis ◽  
2020 ◽  
Vol 52 (15) ◽  
pp. 2224-2232
Author(s):  
Boris A. Trofimov ◽  
Nina K. Gusarova ◽  
Nina I. Ivanova ◽  
Kseniya O. Khrapova ◽  
Pavel A. Volkov ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Green Chemistry ◽  
Green Synthesis ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Solvent Free ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Intramolecular Hydrogen ◽  
Solvent Free Reaction

Tertiary α-hydroxyphosphine oxides have been synthesized via the catalyst- and solvent-free reaction between available secondary phosphine oxides and aliphatic, aromatic and heteroaromatic ketones at 20–62 °C in near to 96–98% yield. The developed method meets the requirements of green chemistry and the PASE (pot, atom, step economy) paradigm. According to quantum-chemical calculations at the B3LYP/6-311++G(d,p) level, the synthesized hydroxyphosphine oxides feature a weak (≈3 kcal·mol–1) O−H···O=P intramolecular hydrogen bond.

scholarly journals Coordination chemistry and catalysis with secondary phosphine oxides

2019 ◽  
Vol 9 (20) ◽  
pp. 5504-5561 ◽  
Author(s):  
Albert Gallen ◽  
Antoni Riera ◽  
Xavier Verdaguer ◽  
Arnald Grabulosa
Keyword(s):  
Coordination Chemistry ◽  
Secondary Phosphine ◽  
Phosphine Oxides

Review on synthesis, coordination chemistry and catalysis with secondary phosphine oxides.

scholarly journals Air and water stable secondary phosphine oxides as diazaphospholene precatalysts

2020 ◽  
Vol 56 (58) ◽  
pp. 8027-8030 ◽  
Author(s):  
Travis Lundrigan ◽  
Chieh-Hung Tien ◽  
Katherine N. Robertson ◽  
Alexander W. H. Speed
Keyword(s):  
Secondary Phosphine ◽  
Phosphine Oxides

Secondary phosphine oxides, which are air and water stable, and purifiable by chromatography generate phosphenium or phosphorus hydride catalysts in situ.

Ph3P-mediated highly selective C(α)–P coupling of quinone monoacetals with R2P(O)H: convenient and practical synthesis of ortho-phosphinyl phenols

2018 ◽  
Vol 20 (22) ◽  
pp. 5111-5116 ◽  
Author(s):  
Ruwei Shen ◽  
Ming Zhang ◽  
Jing Xiao ◽  
Chao Dong ◽  
Li-Biao Han
Keyword(s):  
Coupling Reaction ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Practical Synthesis

The Ph3P-mediated C(α)–P coupling reaction of quinone monoacetals with secondary phosphine oxides is developed to provide an effective method for the synthesis of a wide array of ortho-phosphinyl phenols in good to excellent yields.

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