Oxygen partial pressure effects on the oxidative dehydrogenation of propane

1999 ◽  
Vol 54 (20) ◽  
pp. 4365-4370 ◽  
Author(s):  
D. Creaser ◽  
B. Andersson ◽  
R.R. Hudgins ◽  
P.L. Silveston
2015 ◽  
Vol 80 (3) ◽  
pp. 355-366 ◽  
Author(s):  
Yousef Zaynali ◽  
Seyed Alavi

Supported vanadia catalyst was successfully synthesized using wet impregnation of ?-Alumina to study Propane Oxidative Dehydrogenation (POD). The prepared catalysts were characterized with XRD, BET, and TPR tests. In a broad temperature range (340 to 630?C), effects of vanadia loading (2.7, 5.4, and 9 wt%) and propane to oxygen ratio (3/1 to 1/3) were thoroughly investigated on propane conversion as well as propene yield at atmospheric pressure. Results indicate that by increasing the vanadia content the activity of catalyst increases while selectivity to propene decreases monotonically. As the temperature increases from 340?C to 630?C, yield to propene shows ascending behavior in case of all catalyst samples. Yield to propene shows a climax with changing propane to oxygen ratio from 3/1 to 1/3. The yield increases with increase in oxygen partial pressure of feed until equimolar ratio of propane and oxygen, then it declines with further increase of oxygen partial pressure. A maximum propene yield of 17% was experienced on catalyst with 2.7wt% vanadia at temperatures at 550?C.


Author(s):  
Zeljko S. Kotanjac ◽  
John P. M. Niederer ◽  
Geert F. Versteeg

The yields and selectivities in both the catalyzed and non-catalyzed oxidative dehydrogenation of propane were found to increase with increasing pressure. The results showed that the maximum yields of valuable ODH products could be obtained by adjusting only reactants' partial pressure, while keeping their ratio constant.


2018 ◽  
Vol 435 ◽  
pp. 880-885 ◽  
Author(s):  
Erdal Turgut ◽  
Ömer Çoban ◽  
Sevda Sarıtaş ◽  
Sebahattin Tüzemen ◽  
Muhammet Yıldırım ◽  
...  

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