Volumes of activation for the anation of Pd(II) substituted dien complexes by chloride ion in aqueous solution. A high pressure stopped-flow instrument for studying the kinetics of fast reactions under pressure

1981 ◽  
Vol 50 ◽  
pp. 131-135 ◽  
Author(s):  
R. Van Eldik ◽  
D.A. Palmer ◽  
R. Schmidt ◽  
H. Kelm
Keyword(s):  
Aqueous Solution ◽  
High Pressure ◽  
Chloride Ion ◽  
Stopped Flow ◽  
Fast Reactions ◽  
Kinetics Of

The mechanism of the oxidation of thiocyanate ion by peroxomonosulphate in aqueous solution. II. Kinetics of the reaction

1966 ◽  
Vol 19 (8) ◽  
pp. 1365 ◽  
Author(s):  
RH Smith ◽  
IR Wilson
Keyword(s):  
Aqueous Solution ◽  
Initial Rate ◽  
Stopped Flow ◽  
Thiocyanate Ion ◽  
First Order ◽  
Conductance Method ◽  
Rate Of Reaction ◽  
Kinetics Of

Initial rates of reaction for the above oxidation have been measured by a stopped-flow conductance method. Between pH 2 and 3.6, the initial rate of reaction, R, is given by the expression R{[HSO5-]+[SCN-]} = {kb+kc[H+]}[HSO5-]0[SCN-]20+ka[H+]-1[HSO5]20[SCN-]0 As pH increases, there is a transition to a pH-independent rate, first order in each thiocyanate and peroxomonosulphate concentrations.

Formation kinetics of peroxovanadium(V) complexes in strongly acidic media as studied by a high-pressure stopped-flow technique

1989 ◽  
Vol 157 (1) ◽  
pp. 65-71 ◽  
Author(s):  
Shigenobu Funahashi ◽  
Koji Ishihara ◽  
Masahiko Inamo† ◽  
Motoharu Tanaka
Keyword(s):  
High Pressure ◽  
Stopped Flow ◽  
Acidic Media ◽  
Formation Kinetics ◽  
Kinetics Of
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