Mono-Substitution of iron pentacarbonyl catalyzed by polynuclear iron carbonyl anions

1979 ◽  
Vol 169 (2) ◽  
pp. 191-197 ◽  
Author(s):  
Susan Beda Butts ◽  
D.F. Shriver
Keyword(s):  
Iron Pentacarbonyl ◽  
Iron Carbonyl

Reactions of 1,1,3,3-tetramethyldisilazane with dicobalt octacarbonyl and iron pentacarbonyl. Thermal decomposition of the cobalt and iron carbonyl silazane complexes

1998 ◽  
Vol 47 (12) ◽  
pp. 2455-2462 ◽  
Author(s):  
V. V. Semenov ◽  
E. Yu. Ladilina ◽  
S. Ya. Khorshev ◽  
N. P. Makarenko ◽  
Yu. A. Kurskii ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Iron Pentacarbonyl ◽  
Iron Carbonyl ◽  
Dicobalt Octacarbonyl

scholarly journals On a new Iron carbonyl, and on the action of light and of heat on the Iron carbonyls

1907 ◽  
Vol 79 (527) ◽  
pp. 66-80 ◽  
Keyword(s):  
Liquid Iron ◽  
Carbonyl Iron ◽  
Chemical Properties ◽  
Iron Pentacarbonyl ◽  
Iron Carbonyl ◽  
Physical And Chemical Properties ◽  
Solid Compound ◽  
Iron Carbonyls ◽  
Physical And Chemical ◽  
And Chemical Properties

This paper contains an account of the results of the continuation of the experiments on the action of light on the liquid iron carbonyl (iron penta-carbonyl) and the action of heat on the resulting solid compound, diferro-nonacarbonyl, Fe 2 (CO) 9 , which were described in a paper on “The Physical and Chemical Properties of Iron Carbonyl,” communicated to the Society in 1905. The experiments on the action of light on iron pentacarbonyl under varied conditions have resulted in new and interesting observations, and approximate measurements of the velocity of the reaction induced by light have been made and compared with that of other reactions induced by light.

scholarly journals The physical and chemical properties of iron carbonyl

1905 ◽  
Vol 76 (513) ◽  
pp. 558-577 ◽  
Keyword(s):  
Carbon Monoxide ◽  
Chemical Properties ◽  
Iron Pentacarbonyl ◽  
Iron Carbonyl ◽  
Physical And Chemical Properties ◽  
Analogous Compound ◽  
Physical And Chemical ◽  
And Chemical Properties

This paper contains an account, as promised, of a study of the physical and chemical properties of iron carbonyl, similar to that already communicated to the Society on the properties of the analogous compound of nickel,* to which this forms the sequel. The combination of iron and carbon monoxide was discovered by Drs. Mond and Quincke in 1891, and the resulting compound called iron pentacarbonyl was isolated (as a coloured liquid), and examined by Drs. Mond and Langer in the course of the same year.

Alkylation of Cymantrene with 1-Bromoadamantane Initiated by Iron Pentacarbonyl

INEOS OPEN ◽  
2019 ◽  
Vol 2 (1) ◽  
Author(s):  
Т. Т. Vasil'eva ◽  
◽  
H. H. Hambardzumyan ◽  
N. Е. Mysova ◽  
O. N. Gorunova ◽  
...  
Keyword(s):  
Iron Pentacarbonyl

scholarly journals Facile Organometallic Synthesis of Fe-Based Nanomaterials by Hot Injection Reaction

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1141
Author(s):  
Georgia Basina ◽  
Hafsa Khurshid ◽  
Nikolaos Tzitzios ◽  
George Hadjipanayis ◽  
Vasileios Tzitzios
Keyword(s):  
Room Temperature ◽  
Colloidal Particles ◽  
Iron Pentacarbonyl ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
Organometallic Synthesis ◽  
X Ray ◽  
Transmission Electron ◽  
Hot Injection ◽  
The Stability

Fe-based colloids with a core/shell structure consisting of metallic iron and iron oxide were synthesized by a facile hot injection reaction of iron pentacarbonyl in a multi-surfactant mixture. The size of the colloidal particles was affected by the reaction temperature and the results demonstrated that their stability against complete oxidation related to their size. The crystal structure and the morphology were identified by powder X-ray diffraction and transmission electron microscopy, while the magnetic properties were studied at room temperature with a vibrating sample magnetometer. The injection temperature plays a very crucial role and higher temperatures enhance the stability and the resistance against oxidation. For the case of injection at 315 °C, the nanoparticles had around a 10 nm mean diameter and revealed 132 emu/g. Remarkably, a stable dispersion was created due to the colloids’ surface functionalization in a nonpolar solvent.

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