A tungsten carbide-alumina compound ceramic made by high temperature synthesis

1996 ◽  
Vol 51 (4) ◽  
pp. 44
Author(s):  
Nikolay V. Gromov ◽  
Тatiana B. Medvedeva ◽  
Ivan А. Lukoyanov ◽  
Alekasandr А. Zhdanok ◽  
Vladimir А. Poluboyarov ◽  
...  

Catalytic systems based on tungsten carbide (WnC) containing mainly W2C were obtained by the method of self-propagating high-temperature synthesis from a mechanochemically activated mixture of tungsten oxide, metallic magnesium, carbon black and CaCO3. The phase composition of the formed materials was shown to depend on the amount of CaCO3. The catalytic properties of the materials were tested in the hydrolysis-hydrogenation of cellulose to ethylene glycol (EG) and 1,2-propylene glycol (PG). It was established that in the presence of WnC the main products of the reaction were EG and PG with a ratio of PG/EG – 1.5-1.8. The deposition of nickel nanoparticles on the WnC surface increased the reaction rate and product yields. The maximum total yield of diols was 47.1 mol. %.


2020 ◽  
pp. 31-34
Author(s):  
S. N. Khimukhin ◽  
◽  
V. B. Deev ◽  
E. Kh. Ri ◽  
E. D. Kim ◽  
...  

2011 ◽  
Vol 52 (6) ◽  
pp. 851-854 ◽  
Author(s):  
A. R. Zurnachyan ◽  
Kh. V. Manukyan ◽  
S. L. Kharatyan ◽  
V. A. Matyshak ◽  
R. A. Mnatsakanyan

2004 ◽  
Vol 40 (10) ◽  
pp. 1043-1048 ◽  
Author(s):  
I. P. Borovinskaya ◽  
T. I. Ignat'eva ◽  
V. I. Vershinnikov ◽  
N. V. Sachkova

2011 ◽  
Vol 415-417 ◽  
pp. 226-231
Author(s):  
Xin Wei

Alumina-Tungsten Carbide (Al2O3-WC) composites were synthesized by self-propagating high temperature synthesis (SHS) from a powder mixture of WO3-C-Al. The reaction was carried out in a SHS reactor under static argon gas at a pressure of 0.5 MPa. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The effects of carbon mole ratio in precursor mixture and diluents of NaCl and Al2O3 on the Al2O3-WC conversion were investigated using X-ray diffraction and scanning electron microscope technique. The as-synthesized products of Al2O3-WC2-WC powders were concurrently formed and the reduction of W2C phase was found when added diluents in precursors.


2007 ◽  
Vol 43 (4) ◽  
pp. 239-242
Author(s):  
S. Kh. Suleimanov ◽  
O. A. Dudko ◽  
V. G. Dyskin ◽  
Z. S. Settarova ◽  
M. U. Dzhanklych

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