05/00762 Behavior of a high-capacity steam boiler using heavy fuel oil. Part I: High temperature corrosion

2005 ◽  
Vol 46 (2) ◽  
pp. 112
Author(s):  
Jean-Pierre Stalder ◽  
Peter A. Huber

The use of “clean” fuel is a prerequisite at today’s elevated gas turbine firing temperature, modern engines are more sensitive to high temperature corrosion if there are impurities present in the fuel and/or in the combustion air. It is a common belief that distillate grade fuels are contaminant-free, which is often not true. Frequently operators burning distillates ignore the fuel quality as a possible source of difficulties. This matter being also of concern in plants mainly operated on natural gas and where distillate fuel oil is the back-up fuel. Distillates may contain water, dirt and often trace metals such as sodium, vanadium and lead which can cause severe damages to the gas turbines. Sodium being very often introduced through contamination with seawater during the fuel storage and delivery chain to the plant, and in combination, or with air borne salt ingested by the combustion air. Excursions of sodium in treated crude or heavy fuel oil can occur during unnoticed malfunctions of the fuel treatment plant, when changing the heavy fuel provenience without centrifuge adjustment, or by inadequate fuel handling. For burning heavy fuel, treatment with oil-soluble magnesium fuel additive is state of the art to inhibit hot corrosion caused by vanadium. Air borne salts, sodium, potassium and lead contaminated distillates, gaseous fuels, washed and unwashed crude and residual oil can not be handled by simple magnesium based additives. The addition of elements like silicon and/or chromium is highly effective in reducing turbine blade hot corrosion and hot section fouling. This paper describes field experience with the use of chromium containing fuel additive to reduce high temperature corrosion of hot section parts, as well as the interaction of oil-soluble chromium and magnesium-chromium additives on material behaviour of blades and vanes, and their economical and environmental aspects.


2004 ◽  
Vol 86 (2) ◽  
pp. 89-105 ◽  
Author(s):  
Jorge Barroso ◽  
Félix Barreras ◽  
Javier Ballester

CORROSION ◽  
2001 ◽  
Vol 57 (6) ◽  
pp. 489-496 ◽  
Author(s):  
M. Amaya ◽  
J. Porcayo-Calderon ◽  
L. Martinez

Abstract The performance of Fe-Si coatings and an iron aluminide (FeAl) intermetallic alloy (FeAl40at%+0.1at%B+10vol%Al2O3) in molten salts containing vanadium pentoxide (V2O5) and sodium sulfate (Na2SO4) is reported. Corrosion and fouling by ash deposits containing V2O5 and Na2SO4 are typical corrosion problems in fuel oil-fired electric power units. High-temperature corrosion tests were performed using both electrochemical polarization and immersion techniques. The temperature interval of this study was 600°C to 900°C, and the molten salts were 80wt%V2O5-20wt%Na2SO4. Curves of corrosion current density vs temperature obtained by the potentiodynamic studies are reported, as well as the weight loss vs temperature curves from molten salt immersion tests. Both Fe-Si coatings and FeAl40at%+0.1at%B+10vol%Al2O3 showed good behavior against molten salt corrosion. The final results show the potential of these coatings and alloys to solve the high-temperature corrosion in fuel oil-fired electric power units.


Fuel ◽  
2007 ◽  
Vol 86 (5-6) ◽  
pp. 820-828 ◽  
Author(s):  
Seng-Rung Wu ◽  
Wen-Chen Chang ◽  
Jack Chiao

Volume 1 ◽  
2004 ◽  
Author(s):  
S. M. Camporeale ◽  
F. Casalini ◽  
A. Saponaro

In the last years many research studies have been focused on the features of MILD combustion that is a stable form of combustion, obtained with high temperature reactants and high exhaust gas recirculation and characterized by low flame temperature and, consequently, low Nox emissions. This form of combustion is also characterized by low light emissions (for this reason it is also called “flameless” combustion) and a large range of stable operation. MILD combustion has been already applied in industrial furnaces where ceramic regenerators provide to raise the temperature of the entering diluted air, the main advantages being high efficiency and low emissions. The introduction of MILD combustion in power plants would allow for increasing the temperature of the entering reactants beyond the self-ignition temperature without increasing the NOx emission. The main goals of this technique are low combustion exergy losses, large range of stable combustion, and low NOx emissions. Some experiments have shown that the flameless conditions can be obtained using diluted reactants, even using heavy fuel oil. Good results in terms of NOx emissions and soot formation have been obtained for heavy oil combustion in a 10% oxygen concentration of reactants and combustion chamber inlet temperature of about 900K. In order to meet these conditions, a semiclosed CCGT cycle with high recirculation ratio, suitable for the use of heavy fuel oil, is proposed here, assuming state-of-the-art technologies for gas turbine and steam plant and steam cooling of the turbine blades. The thermodynamic analysis shows that the overall plant efficiency of the new scheme is close to 60% that is about the efficiency that can be obtained in modern CCGT power plant fuelling natural gas.


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