Use of Chromium Containing Fuel Additive to Reduce High Temperature Corrosion of Hot Section Parts

2000 ◽  
Author(s):  
Jean-Pierre Stalder ◽  
Peter A. Huber
Keyword(s):  
High Temperature ◽  
Hot Corrosion ◽  
Gas Turbines ◽  
High Temperature Corrosion ◽  
Fuel Oil ◽  
Fuel Additive ◽  
Fuel Quality ◽  
Common Belief ◽  
Heavy Fuel Oil ◽  
Fuel Treatment

The use of “clean” fuel is a prerequisite at today’s elevated gas turbine firing temperature, modern engines are more sensitive to high temperature corrosion if there are impurities present in the fuel and/or in the combustion air. It is a common belief that distillate grade fuels are contaminant-free, which is often not true. Frequently operators burning distillates ignore the fuel quality as a possible source of difficulties. This matter being also of concern in plants mainly operated on natural gas and where distillate fuel oil is the back-up fuel. Distillates may contain water, dirt and often trace metals such as sodium, vanadium and lead which can cause severe damages to the gas turbines. Sodium being very often introduced through contamination with seawater during the fuel storage and delivery chain to the plant, and in combination, or with air borne salt ingested by the combustion air. Excursions of sodium in treated crude or heavy fuel oil can occur during unnoticed malfunctions of the fuel treatment plant, when changing the heavy fuel provenience without centrifuge adjustment, or by inadequate fuel handling. For burning heavy fuel, treatment with oil-soluble magnesium fuel additive is state of the art to inhibit hot corrosion caused by vanadium. Air borne salts, sodium, potassium and lead contaminated distillates, gaseous fuels, washed and unwashed crude and residual oil can not be handled by simple magnesium based additives. The addition of elements like silicon and/or chromium is highly effective in reducing turbine blade hot corrosion and hot section fouling. This paper describes field experience with the use of chromium containing fuel additive to reduce high temperature corrosion of hot section parts, as well as the interaction of oil-soluble chromium and magnesium-chromium additives on material behaviour of blades and vanes, and their economical and environmental aspects.

Fuel Treatment Chemical Additives Progress Report

1980 ◽  
Vol 102 (4) ◽  
pp. 813-819
Author(s):  
A. E. Bischof
Keyword(s):  
High Temperature ◽  
Combustion Efficiency ◽  
High Temperature Corrosion ◽  
Progress Report ◽  
Fuel Quality ◽  
Chemical Solution ◽  
Case Histories ◽  
Chemical Additives ◽  
Fuel Use ◽  
Fuel Treatment

A detailed discussion of fuel quality as related to associated fuel use problems is presented. The generic chemical solution to the problems is covered with emphasis on the correction of system mechanical and instrumental malfunctions. Three case histories concerning high temperature corrosion, combustion efficiency and deposit accumulation are explored.

Electrochemical Studies on High-Temperature Corrosion of Silicon-Iron Coatings and Iron Aluminide Intermetallic Alloys by Molten Salts

CORROSION ◽  
2001 ◽  
Vol 57 (6) ◽  
pp. 489-496 ◽  
Author(s):  
M. Amaya ◽  
J. Porcayo-Calderon ◽  
L. Martinez
Keyword(s):  
High Temperature ◽  
Molten Salt ◽  
Electric Power ◽  
Molten Salts ◽  
Corrosion Current ◽  
High Temperature Corrosion ◽  
Iron Aluminide ◽  
Fuel Oil ◽  
Silicon Iron ◽  
Salt Corrosion

Abstract The performance of Fe-Si coatings and an iron aluminide (FeAl) intermetallic alloy (FeAl40at%+0.1at%B+10vol%Al2O3) in molten salts containing vanadium pentoxide (V2O5) and sodium sulfate (Na2SO4) is reported. Corrosion and fouling by ash deposits containing V2O5 and Na2SO4 are typical corrosion problems in fuel oil-fired electric power units. High-temperature corrosion tests were performed using both electrochemical polarization and immersion techniques. The temperature interval of this study was 600°C to 900°C, and the molten salts were 80wt%V2O5-20wt%Na2SO4. Curves of corrosion current density vs temperature obtained by the potentiodynamic studies are reported, as well as the weight loss vs temperature curves from molten salt immersion tests. Both Fe-Si coatings and FeAl40at%+0.1at%B+10vol%Al2O3 showed good behavior against molten salt corrosion. The final results show the potential of these coatings and alloys to solve the high-temperature corrosion in fuel oil-fired electric power units.

THE APPLICATION OF FUZZY AHP – VIKOR HYBRID METHOD TO INVESTIGATE THE STRATEGY FOR REDUCING AIR POLLUTION FROM DIESEL POWERED VESSELS

2021 ◽  
Vol 162 (A3) ◽  
Author(s):  
H Demirel ◽  
M Mollaoğlu ◽  
U Bucak ◽  
T Arslan ◽  
A Balin
Keyword(s):  
Air Pollution ◽  
Human Health ◽  
Hybrid Method ◽  
Fossil Fuels ◽  
Fuzzy Ahp ◽  
Maritime Transportation ◽  
Fuel Oil ◽  
Fuel Quality ◽  
Heavy Fuel Oil ◽  
Marine Areas

The negative impact of air pollution on human health had become a vital issue as a result of the increasing use of fossil fuels in recent years. In this context, maritime transportation is one of the most contaminant sectors by using much more fossil fuels. Ships which have a major role in maritime transport, directly affect human health via its emissions, especially in marine areas close to the land such as around the ports, canals, and straits. In this study, strategies were gathered by evaluating International Maritime Organization (IMO) regulations, European Union (EU) recommendations and the applications of the ship owner companies to reduce air pollution stem from ships, and considering the priority perception of these strategies, the effect level of the strategies at the marine areas where ships are approaching the land was analysed by the Fuzzy Analytic Hierarchy Process-Visekriterijumska Optimizacija I Kompromisno Resenje (AHP- VIKOR) hybrid method. As a result of the study, the most effective strategies appeared as “Forbiddance of Heavy Fuel Oil (HFO) usage on Ships” and “Detection of Low Sulphur Fuel Usage by the help of Remote Detector Systems”, and it was seen that these strategies would be most effective in canal or strait passing of the ships. It was also revealed that the relevant expert opinions and IMO regulations meshed together, and it was pointed out the applications for increasing fuel quality.

Corrosion and Protection of Superalloys

2002 ◽  
pp. 287-322
Keyword(s):  
High Temperature ◽  
Hot Corrosion ◽  
Protective Coatings ◽  
High Temperature Corrosion ◽  
Oxide Growth ◽  
Mixed Gas ◽  
Gas Corrosion ◽  
Mixed Gases ◽  
Oxidation And Corrosion ◽  
Associated Data

Abstract Superalloys tend to operate in environments where they are subjected to high-temperature corrosion, oxidation, and the erosive effects of hot gases. This chapter discusses the nature of these attacks and the effectiveness of various protection methods. It describes the primary forms of oxidation, the development of protective oxides, and the conditions associated with mixed gas corrosion and hot corrosion attack. It discusses oxidation and corrosion testing, the equipment used, and various ways to present the associated data. It describes the effect of gaseous oxidation on different alloys, discusses the formation of oxide scale in the presence of mixed gases, and explains how alloy composition contributes to oxide growth. The chapter discusses the underlying chemistry of hot corrosion, how to identify its effects, and how it progresses under various conditions. It also discusses protective coatings, including aluminide diffusion, overlay, and thermal barrier types, and how they perform in different environments based on their ability to tolerate strain.

Hot Corrosion Resistance Properties of Al-Si Coatings Obtained by Slurry Method

2012 ◽  
Vol 326-328 ◽  
pp. 273-278 ◽  
Author(s):  
Agnieszka Kochmańska
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Hot Corrosion ◽  
Protective Coatings ◽  
Cast Steel ◽  
High Temperature Corrosion ◽  
Air Atmosphere ◽  
Before And After ◽  
Slurry Method ◽  
Thermal Shocks

This paper presents the results of research on aluminide protective coatings manufactured on hightemperature creep resistant cast steel. The main purpose of these coatings is protection against the high temperature corrosion, at carburizing and oxidizing potential atmosphere. Coatings were obtained on cast steel type GXNiCrSi 3018 by slurry cementation in air atmosphere. The tests of carburizing and oxidizing were carried out. The structure of the coatings before and after carburizing and oxidizing is described in the present paper. The chemical composition, thickness and microstructure of coatings were determined. These coatings could protect equipment against hot corrosion at carburizing and oxidizing atmosphere and have thermal shocks resistance.

Effect of Chemical Fuel Additives on Liquid Fuel Saving, and Emissions for Heavy Fuel Oil

2016 ◽  
Author(s):  
Ahmed Emara
Keyword(s):  
Mass Flow ◽  
Acoustic Noise ◽  
Combustion Process ◽  
Combustion Characteristics ◽  
Fuel Oil ◽  
Mass Spectrometry Analysis ◽  
Fuel Additive ◽  
Fuel Saving ◽  
Fuel Additives ◽  
Heavy Fuel Oil

As fossil fuel resources are considered non-renewable sources of fuel, they will be totally consumed in the near or far future. Due to the intensive and extensive consumption of these fossil fuels in all life sectors such as transportation, power generation, industrial processes, and residential consumption, it is important to find other new methods to cover this fuel demand. Fuel additives are chemicals used to enhance fuel combustion performance, save fuel amounts required for combustion, and correct deficiencies in power and efficiency during consumption. The fuel additives are blended with the traditional fuel even by parts per million range for controlling chemical contaminants and emission reduction. In the present work, the experimental measurements were done, to evaluate the effect of fuel additive blending with the raw heavy fuel oil (Mazut) on fuel saving which is of a great significance, emissions control, and combustion characteristics as well as the combustion efficiency. These measurements are as follows: initial temperature of Mazut, exhaust gas temperature at the end of combustor, air and fuel mass flow rates to determine the heat load, inlet and outlet temperatures of cooling water, mass flow rate of water, concentration of different exhaust gases, acoustic (noise level) measurements, smoke number, and flame length. These measurements are performed using swirled vanes, co-axial, and double heavy fuel nozzle (1.5 gal/hr for each one) burner with maximum heating load of 550 kW. GC-MS (Gas chromatography-mass spectrometry) analysis was performed by using Hewlett Packard model 5890 equipped with a flame ionization detector (FID) to identify the fuel additives substances within the tested samples. The results reveal that the use of fuel additives improves the combustion characteristics and play an important role in fuel saving as well as emission and combustion process.

Sign in / Sign up

Export Citation Format

Share Document