98/03753 Feasibility analysis of ternary feed mixtures of methane with oxygen, steam, and carbon dioxide for the production of methanol synthesis gas

1998 ◽  
Vol 39 (5) ◽  
pp. 351
2021 ◽  
Vol 25 (12) ◽  
pp. 30-37
Author(s):  
L.G. Pinaeva ◽  
A.S. Noskov

Existing (production of urea, dimethyl carbonate, polypropylene carbonate) and promising (production of methanol, synthesis gas, monomers dedicated to synthesis of polyurethanes and polycarbonate) chemical technologies which any, time soon, may become CO2 based economy for producing motor fuels and basic chemicals have been overviewed. Based on estimates of CO2 removals in these processes, it has been concluded that there is a potential for developing technologies to produce methanol from CO2 to a competitive cost of the target product. It is expected that interest in this process will decrease if stable carbon dioxide conversion catalysts for methane are introduced into the market.


2015 ◽  
Vol 137 (6) ◽  
Author(s):  
Eric R. Morgan ◽  
Thomas L. Acker

A methanol synthesis unit (MSU) that directly converts carbon dioxide and hydrogen into methanol and water was developed and tested. The MSU consists of: a high-pressure side that includes a compressor, a reactor, and a throttling valve; and a low-pressure side that includes a knockout drum, and a mixer where fresh gas enters the system. Methanol and water are produced at high pressure in the reactor and then exit the system under low pressure and temperature in the knockout drum. The remaining, unreacted recycle gas that leaves the knockout drum is mixed with fresh synthesis gas before being sent back through the synthesis loop. The unit operates entirely on electricity and includes a high-pressure electrolyzer to obtain gaseous hydrogen and oxygen directly from purified water. Thus, the sole inputs to the trailer are water, carbon dioxide, and electricity, while the sole outputs are methanol, oxygen, and water. A distillation unit separates the methanol and water mixture on site so that the synthesized water can be reused in the electrolyzer. Here, we describe and characterize the operation of the MSU and offer some possible design improvements for future iterations of the device, based on experience.


2013 ◽  
Vol 451 ◽  
pp. 43-49 ◽  
Author(s):  
Hyun Ook Seo ◽  
Jong Ki Sim ◽  
Kwang-Dae Kim ◽  
Young Dok Kim ◽  
Dong Chan Lim ◽  
...  

1993 ◽  
Vol 17 (1-2) ◽  
pp. 157-165 ◽  
Author(s):  
Yuriko Nitta ◽  
Tomohiro Fujimatsu ◽  
Yasuaki Okamoto ◽  
Toshinobu Imanaka

1989 ◽  
Vol 50 (1) ◽  
pp. 247-263 ◽  
Author(s):  
Carl J. Schack ◽  
Melanie A. McNeil ◽  
Robert G. Rinker

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