Synergetic effect of Pd and Ag dispersed on MgO in the reduction of NO by H2 at room temperature

Author(s):  
Shuichi Naito ◽  
Yoshihiro Tanaka
2016 ◽  
Vol 09 (06) ◽  
pp. 1642009 ◽  
Author(s):  
Jing Zhou ◽  
Yong Zhao ◽  
Lifan Qin ◽  
Chen Zeng ◽  
Wei Xiao

Uniform CoSn(OH)6 hollow nanoboxes and the derivative with Pt loading (Pt/CoSn(OH)6) were herein synthesized and characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). SEM and TEM analyses showed that CoSn(OH)6 possessed mesoporous hollow structure and Pt nanoparticles with size of 2–8[Formula: see text]nm were uniformly dispersed on the surface of CoSn(OH)6 nanoboxes. The performances of the catalysts for the formaldehyde (HCHO) removal at room temperature were evaluated. These Pt/CoSn(OH)6 catalysts exhibited a remarkable catalytic activity as well as stability for room-temperature oxidative decomposition of gaseous HCHO, while the corresponding CoSn(OH)6 only showed adsorption. The synergetic effect between the highly dispersed Pt nanoparticles and the CoSn(OH)6 nanoboxes with mesoporous hollow structure, a large surface area and abundant surface hydroxyl groups is considered to be the main reason for the observed high catalytic activity of Pt/CoSn(OH)6.


2011 ◽  
Vol 214 ◽  
pp. 364-368
Author(s):  
Li Li Ren ◽  
Xiao Mei Pan

Three different kinds of Al2O3 have been added to HZSM-5 for improving its activity towards selective catalytic reduction of NO with CH4 in the presence of excess of oxygen. Higher conversions of NO have been observed for all of the three mixed catalysts, the conversion of which were also found to be higher than that of each separate component of the catalysts. It was concluded that there exists a synergetic effect between Al2O3 and HZSM-5. The addition of Al2O3 can improve the catalytic activity of HZSM-5 by inhibiting the decomposing of NO2 to NO and accelerating the activation of methane. Adsorbed NO2 is then reduced by the activated methane or the intermediates formed from activated methane to N2 over the Brønsted site of zeolite.


2006 ◽  
Vol 117 (4) ◽  
pp. 525-535 ◽  
Author(s):  
S.A. Yashnik ◽  
Z.R. Ismagilov ◽  
V.V. Kuznetsov ◽  
V.V. Ushakov ◽  
V.A. Rogov ◽  
...  

Nano Letters ◽  
2013 ◽  
Vol 13 (12) ◽  
pp. 5938-5943 ◽  
Author(s):  
Seung Ho Jeong ◽  
Sol Kim ◽  
Junho Cha ◽  
Min Soo Son ◽  
Sang Han Park ◽  
...  

1995 ◽  
Vol 9 (4) ◽  
pp. 659-664 ◽  
Author(s):  
Isao Mochida ◽  
Shizuo Kawano ◽  
Motohiro Hironaka ◽  
Shunsuke Yatsunami ◽  
Yozo Korai ◽  
...  

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