Catalytic reduction of NOx in gasoline engine exhaust over copper- and nickel-exchanged X–zeolite catalysts

2001 ◽  
Vol 42 (15-17) ◽  
pp. 2019-2027 ◽  
Author(s):  
Souvik Bhattacharyya ◽  
Randip K Das
ROTASI ◽  
2014 ◽  
Vol 16 (4) ◽  
pp. 48
Author(s):  
Syaiful Syaiful ◽  
Iseu Andriani

Diesel engines many are used as transportation mode in the land and sea compared with gasoline engines due to their high efficiency and durability. However, diesel engine releases much more NOx and soot emissions than that of gasoline engine. NOx is formed from a reaction of Nitrogen and Oxygen at high temperature. If these emissions are breathed into human body resulting respiratory disorders such as emphysema and bronchitis as well as lungs tissue damage. Therefore, NOx emissions controll is required to reduce them reaching under a threshold level. An effective method for controlling NOx emissions produced by the diesel engines is by injecting ammonia obtained from urea into selective catalytic reduction (SCR method) system. Ammonia by means of catalyst reacts with NOx forming Nitrogen (N2) and Water (H2O). Therefore, a chance of each ammonia particle to react with each NOx particle is required to consider. A reaction quality between ammmonia and NOx particles can be increased by improving a mixing index. One of the methods to increase the mixing index is by using a dynamic mixer.There are several factors which influence the increase of mixing index. One of these factors is a location of ammonia injector. Since this work is focused on investigating the effect of ammonia injector location on the mixing index of ammonia to diesel engine exhaust gases which content of NOx emissions


2019 ◽  
Author(s):  
Julian Rudolph ◽  
Christoph R. Jacob

<div> <div> <div> <p>We computationally investigate the mechanism of the reduction half-cycle of the selective catalytic reduction (SCR) of nitrogen oxides with ammonia. We compare both Fe- and Cu-doped zeolite catalysts and aim at exploring all accessible reaction pathways. From our calculations, a comprehensive picture emerges that unifies sev- eral previous mechanistic proposals. We find that both for Fe and for Cu catalysts, different reaction pathways are feasible, but some of the possible reaction pathways differ in these two cases. Our computational results provide a basis for the inter- pretation of in situ spectroscopic investigations that can possibly distinguish the different mechanistic pathways. </p> </div> </div> </div>


2014 ◽  
Vol 118 (19) ◽  
pp. 10204-10212 ◽  
Author(s):  
Dmitry E. Doronkin ◽  
Maria Casapu ◽  
Tobias Günter ◽  
Oliver Müller ◽  
Ronald Frahm ◽  
...  

2020 ◽  
Vol 44 (3) ◽  
pp. 817-831 ◽  
Author(s):  
Junqiang Xu ◽  
Yahua Qin ◽  
Honglin Wang ◽  
Fang Guo ◽  
Jiaqing Xie

This paper highlights the design strategies of the copper-based zeolite catalysts with excellent catalytic activity at low temperature for HC-SCR.


2018 ◽  
Vol 237 ◽  
pp. 263-272 ◽  
Author(s):  
Peirong Chen ◽  
Abhishek Khetan ◽  
Magdalena Jabłońska ◽  
Johannes Simböck ◽  
Martin Muhler ◽  
...  

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