Oxidation of aromatic compounds with UV radiation/ozone/hydrogen peroxide

1997 ◽  
Vol 35 (4) ◽  
Keyword(s):  
Hydrogen Peroxide ◽  
Uv Radiation ◽  
Aromatic Compounds

Iodination of Aromatic Compounds Using Potassium Iodide and Hydrogen Peroxide

2008 ◽  
Vol 38 (22) ◽  
pp. 3894-3902 ◽  
Author(s):  
K. Suresh Kumar Reddy ◽  
N. Narender ◽  
C. N. Rohitha ◽  
S. J. Kulkarni
Keyword(s):  
Hydrogen Peroxide ◽  
Potassium Iodide ◽  
Aromatic Compounds

Water decolorization using UV radiation and hydrogen peroxide: A kinetic study

2001 ◽  
Vol 44 (5) ◽  
pp. 53-60 ◽  
Author(s):  
C.A. Martín ◽  
O.M. Alfano ◽  
A.E. Cassano
Keyword(s):  
Hydrogen Peroxide ◽  
Uv Radiation ◽  
Absorption Rate ◽  
Fulvic Acids ◽  
Photon Absorption ◽  
Contaminant Concentration ◽  
Organic Substances ◽  
Mechanistic Approach ◽  
Natural Contamination ◽  
Kinetics Of

Sometimes, provision of water for domiciliary consumption faces the problem of natural contamination originated by the presence of organic substances such as humic or fulvic acids. Very often, after conventional sanitary treatments this water exhibits a persistent yellowish coloration that affects its use. Moreover, these substances may act as precursors of tri-halomethanes formation during pre-desinfection with chlorine. This paper presents, with a simplified mechanistic approach, the intrinsic reaction kinetics of natural water decolorization employing UV radiation and hydrogen peroxide. The main variables for the model are: contaminant concentration expressed as TOC, hydrogen peroxide concentration and the photon absorption rate.

scholarly journals Photochemical Degradation of Sulfadiazine

2013 ◽  
Vol 39 (3) ◽  
pp. 79-91 ◽  
Author(s):  
Natalia Lemańska-Malinowska ◽  
Ewa Felis ◽  
Joanna Surmacz-Górska
Keyword(s):  
Hydrogen Peroxide ◽  
Uv Radiation ◽  
Hydroxyl Radicals ◽  
Rate Constant ◽  
Photochemical Degradation ◽  
Photochemical Processes

Abstract The photochemical degradation of the sulfadiazine (SDZ) was studied. The photochemical processes used in degradation of SDZ were UV and UV/H2O2. In the experiments hydrogen peroxide was applied at different concentrations: 10 mg/dm3 (2.94*10-4 M), 100 mg/dm3 (2.94*10-3 M), 1 g/dm3 (2.94*10-2 M) and 10 g/dm3 (2.94*10-1 M). The concentrations of SDZ during the experiment were controlled by means of HPLC. The best results of sulfadiazine degradation, the 100% removal of the compound, were achieved by photolysis using UV radiation in the presence of 100 mg H2O2/dm3 (2.94*10-3 M). The determined rate constant of sulfadiazine reaction with hydroxyl radicals kOH was equal 1.98*109 M-1s-1.

Oxidation of aromatic compounds by hydrogen peroxide catalyzed by mononuclear iron(III) complexes

2017 ◽  
Vol 426 ◽  
pp. 564-571 ◽  
Author(s):  
Giselle C. Silva ◽  
Nakédia M.F. Carvalho ◽  
Adolfo Horn ◽  
Elizabeth R. Lachter ◽  
Octavio A.C. Antunes
Keyword(s):  
Hydrogen Peroxide ◽  
Aromatic Compounds ◽  
Mononuclear Iron
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