Temperature dependence of local chain dynamics in atactic polypropylene: a neutron spin-echo study

2001 ◽  
Vol 301 (1-2) ◽  
pp. 157-162 ◽  
Author(s):  
Valeria Arrighi ◽  
C Pappas ◽  
A Triolo ◽  
S Pouget
1986 ◽  
Vol 79 ◽  
Author(s):  
A. Z Akcasu ◽  
B Hammouda ◽  
W. H Stockmayer ◽  
G. Tanaka

AbstractThe Fixman-Kovac formulation of chain dynamics with constraints is used to calculate the first cumulant Q(q) of the dynamic scattering function. This general formalism is applied to the case of freely jointed chains. It is shown that the large q limit (q being the scattering wavenumber) of Q(q) for a chain of N bonds in the absence of hydrodynamic interaction is proportional to the ratio (2N+3)/3(N+l) representing the fraction of unconstrained degrees of freedom of the chain. The inclusion of hydrodynamic interaction seems to enhance the apparent segmental diffusion. The use of constrained chain dynamics has no appreciable effects, however, on the behavior of Q(q) in the small and intermediate q regions for long enough chains. This formalism can be used to interpret neutron (spin echo) scattering experiments from semiflexible polymers in solution.


2015 ◽  
Vol 115 (14) ◽  
Author(s):  
Sebastian Gooßen ◽  
Margarita Krutyeva ◽  
Melissa Sharp ◽  
Artem Feoktystov ◽  
Jürgen Allgaier ◽  
...  

2015 ◽  
Vol 17 (29) ◽  
pp. 19126-19133 ◽  
Author(s):  
Tsuyoshi Yamaguchi ◽  
Takuya Yonezawa ◽  
Shinobu Koda

The frequency-dependent viscosity and conductivity of three imidazolium-based ionic liquids were measured at several temperatures in the MHz region, and the results are compared with the intermediate scattering functions determined by neutron spin echo spectroscopy.


2002 ◽  
Vol 311 (1-2) ◽  
pp. 102-105 ◽  
Author(s):  
S Tasaki ◽  
T Ebisawa ◽  
M Hino ◽  
T Kawai ◽  
D Yamazaki ◽  
...  

Neutron News ◽  
2001 ◽  
Vol 12 (2) ◽  
pp. 4-5
Author(s):  
Thomas Gutberlet ◽  
Catherine Pappas

2016 ◽  
Vol 120 (26) ◽  
pp. 13963-13969 ◽  
Author(s):  
Daria Noferini ◽  
Michael M. Koza ◽  
Peter Fouquet ◽  
Gøran J. Nilsen ◽  
Moureen C. Kemei ◽  
...  

Soft Matter ◽  
2014 ◽  
Vol 10 (36) ◽  
pp. 6926-6930 ◽  
Author(s):  
H. Egger ◽  
G. H. Findenegg ◽  
O. Holderer ◽  
R. Biehl ◽  
M. Monkenbusch ◽  
...  

2000 ◽  
Vol 85 (16) ◽  
pp. 3488-3491 ◽  
Author(s):  
E. M. Forgan ◽  
P. G. Kealey ◽  
S. T. Johnson ◽  
A. Pautrat ◽  
Ch. Simon ◽  
...  

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