Local geometry for two Mn2+ paramagnetic centers in α-LiIO3 crystal

1999 ◽  
Vol 271 (1-4) ◽  
pp. 252-255 ◽  
Author(s):  
Wen-Chen Zheng ◽  
Shao-Yi Wu

The field equations in the neighbourhood of a particle for a spherically symmetric metric in the conformal theory of gravitation put forward by Hoyle & Narlikar are examined. As the theory is conformally invariant, one can use different but physically equivalent conformal frames to study the equations. Previously these equations were studied in a conformal frame which, though suitable far away from the isolated particle, turns out not to be suitable in the neighbourhood of the particle. In the present paper a solution in a conformal frame is obtained that is suitable for considering regions near the particle. The solution thus obtained differs from the previous one in several respects. For example, it has no coordinate singularity for any non-zero value of the radial variable, unlike the previous solution or the Schwarzschild solution. It is also shown with the use of this solution that in this theory distant matter has an effect on local geometry.


2021 ◽  
Vol 125 (12) ◽  
pp. 6773-6786
Author(s):  
Claudio José Magon ◽  
Harold Lozano Zarto ◽  
José Pedro Donoso ◽  
Hellmut Eckert ◽  
Sindy Devis ◽  
...  

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Alexander Ulyanov ◽  
Dmitrii Stolbov ◽  
Serguei Savilov

Abstract Jellyfish-like graphene nanoflakes (GNF), prepared by hydrocarbon pyrolysis, are studied with electron paramagnetic resonance (EPR) method. The results are supported by X-ray photoelectron spectroscopy (XPS) data. Oxidized (GNFox) and N-doped oxidized (N-GNFox) flakes exhibit an extremely high EPR response associated with a large interlayer interaction which is caused by the structure of nanoflakes and layer edges reached by oxygen. The GNFox and N-GNFox provide the localized and mobile paramagnetic centers which are silent in the pristine (GNF p ) and N-doped (N-GNF) samples. The change in the relative intensity of the line corresponding to delocalized electrons is parallel with the number of radicals in the quaternary N-group. The environment of localized and mobile electrons is different. The results can be important in GNF synthesis and for explanation of their features in applications, especially, in devices with high sensitivity to weak electromagnetic field.


Author(s):  
Samrit Luoma ◽  
Juha Majaniemi ◽  
Arto Pullinen ◽  
Juha Mursu ◽  
Joonas J. Virtasalo

AbstractThree-dimensional geological and groundwater flow models of a submarine groundwater discharge (SGD) site at Hanko (Finland), in the northern Baltic Sea, have been developed to provide a geological framework and a tool for the estimation of SGD rates into the coastal sea. The dataset used consists of gravimetric, ground-penetrating radar and shallow seismic surveys, drill logs, groundwater level monitoring data, field observations, and a LiDAR digital elevation model. The geological model is constrained by the local geometry of late Pleistocene and Holocene deposits, including till, glacial coarse-grained and fine-grained sediments, post-glacial mud, and coarse-grained littoral and aeolian deposits. The coarse-grained aquifer sediments form a shallow shore platform that extends approximately 100–250 m offshore, where the unit slopes steeply seawards and becomes covered by glacial and post-glacial muds. Groundwater flow preferentially takes place in channel-fill outwash coarse-grained sediments and sand and gravel interbeds that provide conduits of higher hydraulic conductivity, and have led to the formation of pockmarks on the seafloor in areas of thin or absent mud cover. The groundwater flow model estimated the average SGD rate per square meter of the seafloor at 0.22 cm day−1 in autumn 2017. The average SGD rate increased to 0.28 cm day−1 as a response to an approximately 30% increase in recharge in spring 2020. Sensitivity analysis shows that recharge has a larger influence on SGD rate compared with aquifer hydraulic conductivity and the seafloor conductance. An increase in recharge in this region will cause more SGD into the Baltic Sea.


Author(s):  
Igor Tkach ◽  
Ulf Diederichsen ◽  
Marina Bennati

AbstractElectron paramagnetic resonance (EPR)-based pulsed dipolar spectroscopy measures the dipolar interaction between paramagnetic centers that are separated by distances in the range of about 1.5–10 nm. Its application to transmembrane (TM) peptides in combination with modern spin labelling techniques provides a valuable tool to study peptide-to-lipid interactions at a molecular level, which permits access to key parameters characterizing the structural adaptation of model peptides incorporated in natural membranes. In this mini-review, we summarize our approach for distance and orientation measurements in lipid environment using novel semi-rigid TOPP [4-(3,3,5,5-tetramethyl-2,6-dioxo-4-oxylpiperazin-1-yl)-L-phenylglycine] labels specifically designed for incorporation in TM peptides. TOPP labels can report single peak distance distributions with sub-angstrom resolution, thus offering new capabilities for a variety of TM peptide investigations, such as monitoring of various helix conformations or measuring of tilt angles in membranes. Graphical Abstract


2011 ◽  
Vol 520 (3) ◽  
pp. 904-908 ◽  
Author(s):  
A.V. Marikutsa ◽  
M.N. Rumyantseva ◽  
A.M. Gaskov ◽  
E.A. Konstantinova ◽  
D.A. Grishina ◽  
...  

1974 ◽  
Vol 21 (4) ◽  
pp. 1338-1341
Author(s):  
F. F. Kodzhespirov ◽  
M. F. Bulanyi ◽  
V. I. Volozov
Keyword(s):  

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