The free radical chemistry of tert-butyl formate: rate constants for hydroxyl radical, hydrated electron and hydrogen atom reaction in aqueous solution

2002 ◽  
Vol 65 (4-5) ◽  
pp. 309-315 ◽  
Author(s):  
D.Ransom Hardison ◽  
William J. Cooper ◽  
Stephen P. Mezyk ◽  
David M. Bartels
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Rate Constants ◽  
Hydrated Electron ◽  
Radical Chemistry ◽  
Tert Butyl ◽  
Free Radical Chemistry

Free Radical Chemistry of Disinfection-Byproducts. 1. Kinetics of Hydrated Electron and Hydroxyl Radical Reactions with Halonitromethanes in Water

2006 ◽  
Vol 110 (6) ◽  
pp. 2176-2180 ◽  
Author(s):  
Stephen P. Mezyk ◽  
Teresa Helgeson ◽  
S. Kirkham Cole ◽  
William J. Cooper ◽  
Robert V. Fox ◽  
...  
Keyword(s):  
Free Radical ◽  
Hydroxyl Radical ◽  
Disinfection Byproducts ◽  
Hydrated Electron ◽  
Radical Reactions ◽  
Radical Chemistry ◽  
Free Radical Chemistry ◽  
Kinetics Of

Radiolysis studies on the corrosion inhibitors 1 -hexyn-3-ol, cinnamonitrile, and 1,3-diethyl-2-thiourea

1995 ◽  
Vol 73 (12) ◽  
pp. 2137-2142 ◽  
Author(s):  
A.J. Elliot ◽  
M.P. Chenier ◽  
D.C. Ouellette
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Temperature Dependence ◽  
Rate Constant ◽  
Rate Constants ◽  
Corrosion Inhibitors ◽  
Hydrated Electron

In this publication we report: (i) the rate constants for reaction of the hydrated electron with 1-hexyn-3-ol ((8.6 ± 0.3) × 108 dm3 mol−1 s−1 at 18 °C), cinnamonitrile ((2.3 ± 0.2) × 1010 dm3 mol−1 s−1 at 20 °C), and 1,3-diethyl-2-thiourea ((3.5 ± 0.3) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile and diethylthiourea, the temperature dependence up to 200 °C and 150 °C, respectively, is also reported; (ii) the rate constants for the reaction of the hydroxyl radical with 1-hexyn-3-ol ((5.5 ± 0.5) × 109 dm3 mol−1 s−1 at 20 °C), cinnamonitrile ((9.2 ± 0.3) × 109 dm3 mol−1 s−1 at 21 °C), and diethylthiourea ((8.0 ± 0.8) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile, the temperature dependence up to 200 °C is also reported; (iii) the rate constant for the hydrogen atom reacting with 1-hexyn-3-ol ((4.3 ± 0.4) × 109 dm3 mol−1 s−1 at 20 °C). Keywords: radiolysis, corrosion inhibitors, rate constants.

Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by TiIII and Other Single-Electron-Transfer Metals?

2007 ◽  
Vol 46 (12) ◽  
pp. 1941-1941 ◽  
Author(s):  
Juan M. Cuerva ◽  
Araceli G. Campaña ◽  
José Justicia ◽  
Antonio Rosales ◽  
Juan L. Oller-López ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Free Radical ◽  
Hydrogen Atom ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Chemistry ◽  
Atom Source ◽  
Free Radical Chemistry ◽  
The Ideal

scholarly journals Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by TiIII and Other Single-Electron-Transfer Metals?

2007 ◽  
Vol 119 (12) ◽  
pp. 1985-1985
Author(s):  
Juan M. Cuerva ◽  
Araceli G. Campaña ◽  
José Justicia ◽  
Antonio Rosales ◽  
Juan L. Oller-López ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Free Radical ◽  
Hydrogen Atom ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Chemistry ◽  
Atom Source ◽  
Free Radical Chemistry ◽  
The Ideal

Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by TiIII and Other Single-Electron-Transfer Metals?

2006 ◽  
Vol 118 (33) ◽  
pp. 5648-5652 ◽  
Author(s):  
Juan M. Cuerva ◽  
Araceli G. Campaña ◽  
José Justicia ◽  
Antonio Rosales ◽  
Juan L. Oller-López ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Free Radical ◽  
Hydrogen Atom ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Chemistry ◽  
Atom Source ◽  
Free Radical Chemistry ◽  
The Ideal

Absolute rate constants for the reaction of the hydrated electron, hydroxyl radical and hydrogen atom with chloroacetones in water

2002 ◽  
Vol 65 (4-5) ◽  
pp. 327-334 ◽  
Author(s):  
Jason A. Williams ◽  
William J. Cooper ◽  
Stephen P. Mezyk ◽  
David M. Bartels
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Rate Constants ◽  
Hydrated Electron ◽  
Absolute Rate

Free Radical Chemistry of Disinfection Byproducts. 2. Rate Constants and Degradation Mechanisms of Trichloronitromethane (Chloropicrin)

2007 ◽  
Vol 41 (3) ◽  
pp. 863-869 ◽  
Author(s):  
S. Kirkham Cole ◽  
William J. Cooper ◽  
Robert V. Fox ◽  
Piero R. Gardinali ◽  
Stephen P. Mezyk ◽  
...  
Keyword(s):  
Free Radical ◽  
Rate Constants ◽  
Disinfection Byproducts ◽  
Degradation Mechanisms ◽  
Radical Chemistry ◽  
Free Radical Chemistry
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