scholarly journals Annie Higgins 1957–2014

2015 ◽  
Vol 49 (1) ◽  
pp. 120-121
Author(s):  
Wadad Kadi

Annie Campbell Higgins was born and raised in the Chicago area. After receiving a BA in geography from Northwestern University, she entered the University of Chicago's Department of Near Eastern Languages and Civilizations (NELC) in 1988 and graduated with a PhD in Islamic thought in 2001, having been awarded the prestigious Stuart Tave Award in the Humanities. During this period, she taught Arabic language and several Middle Eastern subjects at the University of Chicago, Loyola University, the University of Illinois in Chicago, the College of William and Mary, and the University of Florida. After graduation she held tenure-track positions in Arabic literature and language at Wayne State University and then at the College of Charleston. The key to Annie's academic career was her love of and commitment to the study of Arabic language and culture. Even before entering NELC, she had spent a year in Egypt (1985–86) studying Arabic and making a point of mixing with Egyptians, learning about their culture and speaking their dialect with enthusiasm.

Author(s):  
Douglass Taber

Since five-membered ring ethers often do not show good selectivity on equilibration, single diastereomers are best formed under kinetic control. Aaron Aponick of the University of Florida demonstrated (Organic Lett. 2008, 10, 669) that under gold catalysis, the allylic alcohol 1 cyclized to 2 with remarkable diastereocontrol. Six-membered rings also formed with high cis stereocontrol. Ian Cumpstey of Stockholm University showed (Chem. Commun. 2008, 1246) that with protic acid, allylic acetates such as 3 cyclized with clean inversion at the allylic center, and concomitant debenzylation. J. Stephen Clark of the University of Glasgow found (J. Org. Chem. 2008, 73, 1040) that Rh catalyzed cyclization of 5 proceeded with high selectivity for insertion into Ha, leading to the alcohol 6. Saumen Hajra of the Indian Institute of Technology, Kharagpur took advantage (J. Org. Chem. 2008, 73, 3935) of the reactivity of the aldehyde of 7, effecting selective addition of 7 to 8, to deliver, after reduction, the lactone 9. Tomislav Rovis of Colorado State University observed (J. Org. Chem. 2008, 73, 612) that 10 could be cyclized selectively to either 11 or 12. Nadège Lubin-Germain, Jacques Uziel and Jacques Augé of the University of Cergy- Pontoise devised (Organic Lett. 2008, 10, 725) conditions for the indium-mediated coupling of glycosyl fluorides such as 13 with iodoalkynes such as 14 to give the axial C-glycoside 15. Katsukiyo Miura and Akira Hosomi of the University of Tsukuba employed (Chemistry Lett. 2008, 37, 270) Pt catalysis to effect in situ equilibration of the alkene 16 to the more stable regioisomer. Subsequent condensation with the aldehyde 17 led via Prins cyclization to the ether 18. Paul E. Floreancig of the University of Pittsburgh showed (Angew. Chem. Int. Ed. 2008, 47, 4184) that Prins cyclization could be also be initiated by oxidation of the benzyl ether 19 to the corresponding carbocation. Chan-Mo Yu of Sungkyunkwan University developed (Organic Lett. 2008, 10, 265) a stereocontrolled route to seven-membered ring ethers, by Pd-mediated stannylation of allenes such as 21, followed by condensation with an aldehyde.


Author(s):  
Tristan H. Lambert

A reductive radical cyclization of tetrahydropyran 1 to form bicycle 2 using iron(II) chloride in the presence of NaBH4 was reported (Angew. Chem. Int. Ed. 2012, 51, 6942) by Louis Fensterbank and Cyril Ollivier at the University of Paris and Anny Jutand at the Ecole Normale Supérieure. The enantioselective conversion of tetrahydrofuran 3 to spirocycle 5 via iminium ion-catalyzed hydride transfer/cyclization was developed (Angew. Chem. Int. Ed. 2012, 51, 8811) by Yong-Qiang Tu at Lanzhou University. Daniel Romo at Texas A&M University showed (J. Am. Chem. Soc. 2012, 134, 13348) that enantioenriched tricyclic β-lactone 8 could be readily prepared via dyotropic rearrangement of the diketoacid 6 under catalysis by chiral Lewis base 7. A dyotropic rearrangement was also utilized (Angew. Chem. Int. Ed. 2012, 51, 6984) by Zhen Yang at Peking University, Tuoping Luo at H3 Biomedicine in Cambridge, MA, and Yefeng Tang at Tsinghua University for the conversion of 9 to the bicyclic lactone 10. In terms of the enantioselective synthesis of β-lactones, Karl Scheidt at Northwestern University found that NHC catalyst 12 effects (Angew. Chem. Int. Ed. 2012, 51, 7309) the dynamic kinetic resolution of aldehyde 11 to furnish the lactone 13 with very high ee. Meanwhile, Xiaomeng Feng at Sichuan University has developed (J. Am Chem. Soc. 2012, 134, 17023) a rare example of an enantioselective Baeyer-Villiger oxidation of 4-alkyl cyclohexanones such as 14. The diastereoselective preparation of tetrahydropyran 18 by Lewis acid-promoted cyclization of cyclopropane 17 was accomplished (Org. Lett. 2012, 14, 6258) by Jin Kun Cha at Wayne State University. Stephen J. Connon at the University of Dublin reported (Chem. Commun. 2012, 48, 6502) the formal cycloaddition of aryl succinic anhydrides such as 18 with aldehydes to produce γ-butyrolactones, including 20, in high ee. The stereodivergent cyclization of 21 via desilylation-induced heteroconjugate addition to produce the complex tetrahydropyran 22 was discovered (Org. Lett. 2012, 14, 5550) by Paul A. Clarke at the University of York. Remarkably, while TFA produced a 13:1 diastereomeric ratio in favor of the cis diastereomer 22, the use of TBAF resulted in complete reversal of diastereoselectivity.


Author(s):  
Douglass F. Taber

Carlo Siciliano and Angelo Liguori of the Università della Calabria showed (J. Org. Chem. 2012, 77, 10575) that an amino acid 1 could be both protected and activated with Fmoc-Cl, so subsequent exposure to diazomethane delivered the Fmoc-protected diazo ketone 2. Pei-Qiang Huang of Xiamen University activated (Angew. Chem. Int. Ed. 2012, 51, 8314) a secondary amide 3 with triflic anhydride, then added an alkyl Grignard reagent with CeCl3 to give an intermediate that was reduced to the amine 4. John C. Walton of the University of St. Andrews found (J. Am. Chem. Soc. 2012, 134, 13580) that under irradiation, titania could effect the decarboxylation of an acid 5 to give the dimer 6. Jin Kun Cha of Wayne State University demonstrated (Angew. Chem. Int. Ed. 2012, 51, 9517) that a zinc homoenolate derived from 7 could be transmetalated, then coupled with an electrophile to give the alkylated product 8. The Ramberg-Bäcklund reaction is an underdeveloped method for the construction of alkenes. Adrian L. Schwan of the University of Guelph showed (J. Org. Chem. 2012, 77, 10978) that 10 is a particularly effective brominating agent for this transformation. Daniel J. Weix of the University of Rochester coupled (J. Org. Chem. 2012, 77, 9989) the bromide 12 with the allylic carbonate 13 to give 14. The Julia-Kocienski coupling, illustrated by the addition of the anion of 16 to the aldehyde 15, has become a workhorse of organic synthesis. In general, this reaction is E selective. Jirí Pospísil of the University Catholique de Louvain demonstrated (J. Org. Chem. 2012, 77, 6358) that inclusion of a K+-sequestering agent switched the selectivity to Z. Yoichiro Kuninobu, now at the University of Tokyo, and Kazuhiko Takai of Okayama University constructed (Org. Lett. 2012, 14, 6116) the tetrasubstituted alkene 20 with high geometric control by the Re-catalyzed addition of 19 to the alkyne 18. André B. Charette of the Université de Montréal converted (Org. Lett. 2012, 14, 5464) the allylic halide 21 to the alkyne 22 by displacement with iodoform followed by elimination. In an elegant extension of his studies with alkyl tosylhydrazones, Jianbo Wang of Peking University added (J. Am. Chem. Soc. 2012, 134, 5742) an alkyne 24 to 23 to give 25.


2020 ◽  
pp. 249-251

This anthology stems from a 2014 conference at the University of Maryland, which focused on how American Jews provided material aid to Holocaust refugees during and after the Holocaust, and also how they began to cope with the catastrophe. This coping involved both an imagining and a re-imagining of “the old country,” a reevaluation of the places American Jews had left behind in more or less normal circumstances before the First World War but in increasingly desperate circumstances after 1918 and, again, after 1939. American Jews who had come to the United States before the 1920s maintained ties with their former communities in Central and Eastern Europe, ties that were fostered by efforts to remain in touch with family and friends and, more generally, with the world’s most populous Jewish communities. Those efforts were aided by the ...


2008 ◽  
Vol 58 ◽  
pp. 173-218
Author(s):  
Andrew Brown

AbstractBetween the late 1940s and the 1970s, John Manuel Cook was heavily involved in the archaeology of Anatolia. In 1976 he retired from the University of Bristol and the following year donated a collection of ceramics and other small finds procured during the course of his academic career. These form the core of the Bristol University Near Eastern and Mediterranean Collections (BUNEM). Despite Cook's extensive published record, the majority of these archaeological finds, which formed one of his primary archaeological datasets, never received any form of publication. This article reunites for the first time the Anatolian material donated by Cook to the University of Bristol in 1977 with his published record. In so doing, a glimpse can be gained into the methodologies employed in Anatolian field survey prior to the 1980s, and it will be suggested that collections such as this, despite their many associated difficulties, are a potentially useful source of archaeological data. Furthermore, this will allow some insight into how Cook reached the conclusions he did and consequently why his role in Anatolian archaeology should rightly be acknowledged.


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