On the measurement of the critical potentials of gases

In all methods of measuring excitation and ionisation potentials which are in common use the current-voltage characteristic curves of the apparatus are plotted. In the absence of gas these curves are smooth, but on the admission of gas at a suitable pressure sharp upward bends occur at definite voltages, which are interpreted as the critical potentials of the gas. In a variation by Franck and Hertz, the so-called inelastic impact method, these bends are downward, the critical points being represented by maxima.