A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal–Organic Framework Bearing Linear Cd3 Secondary Building Units

2018 ◽  
Vol 19 (2) ◽  
pp. 724-729 ◽  
Author(s):  
Meng-Yao Chao ◽  
Jing Chen ◽  
Zhi-Min Hao ◽  
Xiao-Yan Tang ◽  
Lifeng Ding ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Conversion Scheme ◽  
Organic Framework

Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal–organic framework via the hetero-metal doping of the linear trimetallic secondary building unit

2018 ◽  
Vol 47 (38) ◽  
pp. 13722-13729 ◽  
Author(s):  
Meng-Yao Chao ◽  
Jing Chen ◽  
David J. Young ◽  
Wen-Hua Zhang ◽  
Jian-Ping Lang
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Secondary Building Unit ◽  
Metal Doping ◽  
Building Unit ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Doping of Co2+ in the linear Cd3 cluster secondary building units lowers the single-crystal to single-crystal conversion reactivity of the resulting metal–organic framework.

scholarly journals Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

2018 ◽  
Vol 19 (1) ◽  
pp. 506-512 ◽  
Author(s):  
Sylvia L. Hanna ◽  
Xuan Zhang ◽  
Ken-ichi Otake ◽  
Riki J. Drout ◽  
Peng Li ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Crystal Phase ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

An N,N′-diethylformamide solvent-induced conversion cascade within a metal–organic framework single crystal

2020 ◽  
Vol 56 (44) ◽  
pp. 5877-5880
Author(s):  
Jing Chen ◽  
Meng-Yao Chao ◽  
Yan Liu ◽  
Bo-Wei Xu ◽  
Wen-Hua Zhang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

A two-dimensional metal–organic framework undergoes four-step single-crystal to single-crystals conversions, including a three-step DEF-induced cascade conversion to shuttle back to its original connectivity.

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Two-Dimensional Metal–Organic Framework Nanosheets as an Enzyme Inhibitor: Modulation of the α-Chymotrypsin Activity

2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Chymotrypsin Activity ◽  
Metal Organic ◽  
Organic Framework
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