Small Molecules, Big Effects: Tuning Adsorption and Catalytic Properties of Metal–Organic Frameworks

2021 ◽  
Vol 33 (4) ◽  
pp. 1444-1454
Author(s):  
Xinyao Liu ◽  
Kent O. Kirlikovali ◽  
Zhijie Chen ◽  
Kaikai Ma ◽  
Karam B. Idrees ◽  
...  
Keyword(s):  
Small Molecules ◽  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO2 reduction by H2

2021 ◽  
Author(s):  
Cornelia Elizabeth Pompe ◽  
Petra Agota Szilagyi
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Catalytically Active ◽  
Metal Organic ◽  
Cu Nanoclusters

Metal-organic frameworks are promising host supporting matrices for catalytically active guest. In particular, their crystallinity renders them desirable as their pores may act as atom-precise templates for the growth of...

Adsorption of Small Molecules on Cu3(btc)2 and Cu3–xZnx(btc)2 Metal–Organic Frameworks (MOF) As Studied by Solid-State NMR

2013 ◽  
Vol 117 (15) ◽  
pp. 7703-7712 ◽  
Author(s):  
Farhana Gul-E-Noor ◽  
Matthias Mendt ◽  
Dieter Michel ◽  
Andreas Pöppl ◽  
Harald Krautscheid ◽  
...  
Keyword(s):  
Solid State ◽  
Small Molecules ◽  
Solid State Nmr ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Metal–Organic Framework Hybrid Materials and Their Applications

Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 325 ◽  
Author(s):  
Joshua Sosa ◽  
Timothy Bennett ◽  
Katherine Nelms ◽  
Brandon Liu ◽  
Roberto Tovar ◽  
...  
Keyword(s):  
Small Molecules ◽  
Hybrid Materials ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Superior Performance ◽  
Separation Energy ◽  
New Materials ◽  
Metal Organic ◽  
Covalent Modifications

The inherent porous nature and facile tunability of metal–organic frameworks (MOFs) make them ideal candidates for use in multiple fields. MOF hybrid materials are derived from existing MOFs hybridized with other materials or small molecules using a variety of techniques. This led to superior performance of the new materials by combining the advantages of MOF components and others. In this review, we discuss several hybridization methods for the preparation of various MOF hybrids with representative examples from the literature. These methods include covalent modifications, noncovalent modifications, and using MOFs as templates or precursors. We also review the applications of the MOF hybrids in the fields of catalysis, drug delivery, gas storage and separation, energy storage, sensing, and others.

Flexible luminescent non-lanthanide metal–organic frameworks as small molecules sensors

2021 ◽  
Author(s):  
Sajal Khatua ◽  
Chidharth Krishnaraj ◽  
Debendra Chandra Baruah ◽  
Pascal Van Der Voort ◽  
Himanshu Sekhar Jena
Keyword(s):  
Small Molecules ◽  
Small Molecule ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Flexible Structure ◽  
Metal Organic ◽  
Lanthanide Metal

Non-lanthanide metal–organic frameworks with flexible structure and luminescence properties are systematically discussed as potential small molecule sensors.

Ln3+ post-functionalized metal–organic frameworks for color tunable emission and highly sensitive sensing of toxic anions and small molecules

2016 ◽  
Vol 40 (5) ◽  
pp. 4654-4661 ◽  
Author(s):  
Ji-Na Hao ◽  
Bing Yan
Keyword(s):  
Small Molecules ◽  
White Light ◽  
Light Emission ◽  
Metal Organic Frameworks ◽  
White Light Emission ◽  
Luminescent Sensors ◽  
Highly Sensitive ◽  
Color Tunable ◽  
Metal Organic ◽  
Tunable Emission

Ln3+-functionalized MOFs with tunable color and white-light emission were fabricated and developed as luminescent sensors for anions and small molecules.

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