Molecular-Level Structural Insight into Clarified Oil by Nuclear Magnetic Resonance (NMR) Spectroscopy: Estimation of Hydrocarbon Types and Average Structural Parameters

2017 ◽  
Vol 31 (7) ◽  
pp. 7682-7692 ◽  
Author(s):  
Sujit Mondal ◽  
Anil Yadav ◽  
Ravindra Kumar ◽  
Veena Bansal ◽  
S. K. Das ◽  
...  
2019 ◽  
Vol 13 (01) ◽  
pp. 124-128 ◽  
Author(s):  
Komal Zia ◽  
Talal Siddiqui ◽  
Saqib Ali ◽  
Imran Farooq ◽  
Muhammad Sohail Zafar ◽  
...  

AbstractNuclear magnetic resonance (NMR) spectroscopy is one of the most significant analytical techniques that has been developed in the past few decades. A broad range of biological and nonbiological applications ranging from an individual cell to organs and tissues has been investigated through NMR. Various aspects of this technique are still under research, and many functions of the NMR are still pending a better understanding and acknowledgment. Therefore, this review is aimed at providing a general overview of the main principles, types of this technique, and the advantages and disadvantages of NMR spectroscopy. In addition, an insight into the current uses of NMR in the field of medicine and dentistry and ongoing developments of NMR spectroscopy for future applications has been discussed.


HortScience ◽  
1995 ◽  
Vol 30 (4) ◽  
pp. 889C-889
Author(s):  
Vincent M. Russo ◽  
John Wright

Understanding carbon metabolism can provide insight into physiological processes regulating yield, senescence, and resistance to pathogens in sweet corn (Zea mays L.). This study was conducted to determine if nuclear magnetic resonance (NMR) spectroscopy could be used to monitor changes in carbon metabolism at various growth stages in the shrunken-2 sweet corn cultivar Illini Gold. The 7th, 9th, and 11th stalk internodes were excised at midwhorl (V9), tassel emergence, 50% silking, and fresh-market harvest stages. The rind was removed and the sap expressed. Carbon-NMR spectroscopy was conducted with a 200.7 MHz machine on the expressed sap. From V9 through 50% silking, peaks in spectra were uniformly grouped from ≈61 to ≈104 ppm. At fresh-market stage, additional peaks were found in the spectra at ≈17 to ≈20 ppm, with the majority of peaks found from ≈57 to ≈104 ppm. The biological importance of these changes in carbon metabolism in sweet corn are not clear. Efforts are under way to identify the carbon-based compounds associated with the peaks.


2018 ◽  
Vol 11 (1) ◽  
pp. 485-508 ◽  
Author(s):  
Sharon E. Ashbrook ◽  
John M. Griffin ◽  
Karen E. Johnston

The sensitivity of nuclear magnetic resonance (NMR) spectroscopy to the local atomic-scale environment offers great potential for the characterization of a diverse range of solid materials. Despite offering more information than its solution-state counterpart, solid-state NMR has not yet achieved a similar level of recognition, owing to the anisotropic interactions that broaden the spectral lines and hinder the extraction of structural information. Here, we describe the methods available to improve the resolution of solid-state NMR spectra and the continuing research in this area. We also highlight areas of exciting new and future development, including recent interest in combining experiment with theoretical calculations, the rise of a range of polarization transfer techniques that provide significant sensitivity enhancements, and the progress of in situ measurements. We demonstrate the detailed information available when studying dynamic and disordered solids and discuss the future applications of solid-state NMR spectroscopy across the chemical sciences.


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