scholarly journals Deactivation of a CoMo Catalyst during Catalytic Hydropyrolysis of Biomass. Part 2. Characterization of the Spent Catalysts and Char

2019 ◽  
Vol 33 (12) ◽  
pp. 12387-12402 ◽  
Author(s):  
M. Z. Stummann ◽  
M. Høj ◽  
B. Davidsen ◽  
L. P. Hansen ◽  
P. Beato ◽  
...  
2019 ◽  
Vol 33 (12) ◽  
pp. 12374-12386 ◽  
Author(s):  
M. Z. Stummann ◽  
M. Høj ◽  
A. B. Hansen ◽  
P. Beato ◽  
P. Wiwel ◽  
...  

2011 ◽  
Vol 236-238 ◽  
pp. 538-542
Author(s):  
Yong Jun Liu

The deactivation behavior of industrial hydrodemetallization catalysts was investigated in the presented work. The main objective of the study is to contribute to a better understanding of the nature of the coke and metal deposition on the used catalysts by applying chemical analysis and various advanced analytical techniques, such as X-ray diffraction analysis (XRD), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and solid-state carbon-13 nuclear magnetic resonance spectroscopy (13C NMR). The results are discussed scientifically based on the physico–chemical properties of origin and used catalysts.


2013 ◽  
Vol 31 (5) ◽  
pp. 697-711 ◽  
Author(s):  
Qingtao Wang ◽  
Hong Lu ◽  
Linxiang Jiang ◽  
Ping'an Peng ◽  
Jinzhong Liu ◽  
...  

2019 ◽  
pp. 23-30 ◽  
Author(s):  
A. S. Yasinskiy ◽  
◽  
Sai Krishna Padamata ◽  
P. V. Polyakov ◽  
D. Yu. Varyukhin ◽  
...  

2021 ◽  
Vol 3 (1) ◽  
pp. 177-187
Author(s):  
Neha Nagar ◽  
◽  
Himanshi Garg ◽  
Chandra Sekhar Gahan ◽  
◽  
...  

The present study aims for characterization and classification of five different spent petroleum refinery catalysts followed by metal recovery via bioleaching. The nomenclature given to the different spent catalyst (SC) is SC1, SC2, SC3, SC4 and SC5 collected from an Indian petroleum refinery. All spent catalysts were crushed and ground prior to their characterization by X-Ray Fluorescence for chemical composition followed by X-Ray Diffraction and Scanning Electron Microscopy-Energy Dispersive X-Ray Spectroscopy for their mineralogy. Further, all five spent catalysts were classified based upon their chemical composition and mineralogy. Metal recovery from the spent catalysts was carried out by bioleaching by a mixed microbial consortium of iron and Sulphur oxidizing microorganisms. Most of the spent catalysts showed very significant metal recovery with respect to Ni, Cu, Cr, Mo, Zn, Sr and Ti. The study provides a possible metal recovery route via bioleaching for further testing and scaling up.


Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 721
Author(s):  
Michael J. Stellato ◽  
Giada Innocenti ◽  
Andreas S. Bommarius ◽  
Carsten Sievers

Cracking of propyl side chains from 4-propylphenol, a model compound for lignin monomers, is studied for a commercial ZSM-5 zeolite catalyst. The decline of 4-propylphenol conversion with time on stream can be delayed by co-feeding water. FTIR spectroscopy shows the formation of chemisorbed phenolates during reactions and significant amounts of phenolics are detected by GC-MS of the extract from the spent catalysts. Thus, chemisorbed phenolates are identified as the main reason for deactivation in the absence of water. Regardless of the amount of co-fed water, substituted monoaromatics and polyaromatic species are formed. Comprehensive characterization of the spent catalysts including Raman and solid-state 27Al NMR spectroscopy, and thermogravimetric analysis points to a combination of deactivation processes. First, phenolates bind to Lewis acid sites within the zeolite framework and hinder diffusion unless they are hydrolyzed by water. In addition, light olefins created during the cracking process react to form a polyaromatic coke that deactivates the catalyst more permanently.


Author(s):  
Sungyoon Jung ◽  
Nathan Reed ◽  
Gregory Yablonsky ◽  
Pratim Biswas

Pd-TiO2 catalysts with five Pd loadings were synthesized using a flame aerosol reactor. Studies of the initial and spent catalysts demonstrate that Pd loading impacted the size of Pd sub-nano...


2010 ◽  
Vol 163 (3) ◽  
pp. 389-394 ◽  
Author(s):  
Songbo He ◽  
Chenglin Sun ◽  
Xu Yang ◽  
Bin Wang ◽  
Xihai Dai ◽  
...  

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