Experimental Solubility Approach to Determine PDMS–Water Partition Constants and PDMS Activity Coefficients

2016 ◽  
Vol 50 (6) ◽  
pp. 3047-3054 ◽  
Author(s):  
Sharon Grant ◽  
Veronika J. Schacht ◽  
Beate I. Escher ◽  
Darryl W. Hawker ◽  
Caroline Gaus



1994 ◽  
Vol 59 (8) ◽  
pp. 1738-1744
Author(s):  
Vladislav Holba

The solubilities of tetraalkylammonium dianilinetetraisothiocyanatochromates(III) (alkyl = methyl, ethyl, 1-propyl, and 1-butyl) in water, water - methanol, water - tert-butyl alcohol and water - acetonitrile solutions were measured at 25 °C. The results were used to evaluate the activity coefficients and Gibbs energies of transfer of the saturating salts from water to the mixed systems. The Gibbs energies of transfer of the [Cr(C6H5NH2)2(NCS)4]- ion were obtained by means of known ionic transfer functions for the tetraalkylammonium ions based on the TATB assumption.



1989 ◽  
Vol 54 (11) ◽  
pp. 2840-2847 ◽  
Author(s):  
Ivona Malijevská ◽  
Alena Maštalková ◽  
Marie Sýsová

Isobaric equilibrium data (P = 101.3 kPa) for the system cyclohexane-acetic acid-propionic acid have been measured by two different analytical techniques. Activity coefficients calculated by simultaneous solving of equations for the chemical and phase equilibria were subjected to a consistency test based on inaccuracies determined from the error propagation law, and were correlated by Wilson’s equation. The activity coefficients measured were compared with those calculated from binary vapour-liquid equilibrium data and with values predicted by the UNIFAC method.



Author(s):  
Rabindra N. Roy ◽  
James J. Gibbons ◽  
Lisa K. Ovens ◽  
Greg A. Bliss ◽  
James J. Hartley


1996 ◽  
Vol 29 (4) ◽  
pp. 588-593
Author(s):  
Seiya Hirohama ◽  
Dai Takeda ◽  
Mamoru Iwasaki ◽  
Kazushige Kawamura


Author(s):  
Xiaoxi Liu ◽  
Douglas A. Day ◽  
Jordan E. Krechmer ◽  
Paul J. Ziemann ◽  
Jose L. Jimenez


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