Poly(dimethylsiloxane) as Interphase in Carbon Fiber-Reinforced Epoxy Resin: Topographical Analysis and Single-Fiber Pull-Out Tests

2019 ◽  
Vol 58 (51) ◽  
pp. 23143-23153 ◽  
Author(s):  
Anna Becker-Staines ◽  
Wolfgang Bremser ◽  
Thomas Tröster
2013 ◽  
Vol 80 (2) ◽  
Author(s):  
Yin Yao ◽  
Shaohua Chen

Surface modifications are known as efficient technologies for advanced carbon fibers to achieve significant improvement of interface adhesion in composites, one of which is to increase the surface roughness in the fiber's longitudinal direction in practice. As a result, many microridges and grooves are produced on carbon fiber's surfaces. How does the surface roughness influence the carbon fiber's pull-out behavior? Are there any restrictions on the relation between the aspect ratio and surface roughness of fibers in order to obtain an optimal interface? Considering the real morphology on carbon fiber's surface, i.e., longitudinal roughness, an improved shear-lag theoretical model is developed in this paper in order to investigate the interface characteristics and fiber pull-out for carbon fiber-reinforced thermosetting epoxy resin (brittle) composites. Closed-form solutions to the carbon fiber stress are obtained as well as the analytical load-displacement relation during pullout, and the apparent interfacial shear strength (IFSS). It is found that the interfacial adhesion and the apparent IFSS are effectively strengthened and improved due to the surface roughness of carbon fibers. Under a given tensile load, an increasing roughness will result in a decreasing fiber stress in the debonded zone and a decreasing debonded length. Furthermore, it is interesting to find that, for a determined surface roughness, an optimal aspect ratio, about 30∼45, of carbon fibers exists, at which the apparent IFSS could achieve the maximum. Comparison to the existing experiments shows that the theoretical model is feasible and reasonable to predict the experimental results, and the theoretical results should have an instructive significance for practical designs of carbon/epoxy composites.


Author(s):  
J. Jäger ◽  
M.G.R. Sause ◽  
F. Burkert ◽  
J. Moosburger-Will ◽  
M. Greisel ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1866
Author(s):  
Chun Pei ◽  
Peiheng Guo ◽  
Ji-Hua Zhu

Preserving the integrity of carbon fibers when recycling carbon-fiber-reinforced plastics (CFRPs) has been unfeasible due to the harsh reaction conditions required to remove epoxy resin matrixes, which adversely affect the properties of carbon fibers. We establish a practicable and environmentally friendly reclamation strategy for carbon fibers. Carbon fibers are recycled from waste CFRPs by an electrochemical catalytic reaction with the assistance of phosphotungstic acid (PA), which promotes the depolymerization of diglycidyl ether of bisphenol A/ethylenediamine (DGEBA/EDA) epoxy resin. The removal rate, mechanical strength, and microstructure of the recycled carbon fibers are analyzed to explore the mechanism of the electrochemical treatment. The influence of three factors—current density, PA concentration, and reaction time—are studied via an orthogonal method. Range analysis and variance analysis are conducted to investigate the significance of the factors. The optimal conditions are determined accordingly. The underlying CFRP degradation mechanism is also investigated.


2014 ◽  
Vol 783-786 ◽  
pp. 2509-2516 ◽  
Author(s):  
Fabrizio Quadrini

Shape memory composites and structures were produced by using carbon fiber reinforced prepregs and a shape memory epoxy resin. The matrix of the prepregs was an epoxy resin as well but without remarkable shape memory properties. This way, two different technical solutions were adopted. Shape memory composite tubes and plates were made by adding a shape memory layer between two carbon fiber reinforced skins. An optimal adhesion between the different layers was achieved thanks to the compatibility of the prepreg matrix and the shape memory material. Shape memory composite structures were also produced by joining composite shells with shape memory foams. Mechanical, dynamic mechanical and shape recovery tests were carried out to show the properties of the composite materials and structures. Results confirm the ability of this class of materials to easily change their shape without affecting the mechanical stiffness of the recovered structures.


2011 ◽  
Vol 462-463 ◽  
pp. 207-212 ◽  
Author(s):  
Hideaki Katogi ◽  
Kenichi Takemura ◽  
Yoshinobu Shimamura

Water absorption behavior and flexural strength properties of carbon fiber reinforced plastics (CFRP) under hot-wet environment were examined. Those of epoxy resin were also examined for reference. Weight gains of CFRP and epoxy resin were measured after immersion in distilled water at temperatures under 90°C. Quasi-static flexural tests of CFRP and epoxy resin were conducted after immersion for 180 days. Weight gains of CFRP and epoxy resin increased with increasing water temperature. After immersion for 180 days at 90°C, weight gain of CFRP became 3.3times higher and that of epoxy resin was 2.3 times higher than that at RT, respectively. When CFRP and epoxy resin were immersed in distilled water at 90°C, weight gains of CFRP and epoxy resin increased and then decreased. Flexural strengths of CFRP and epoxy resin decreased in distilled water at temperatures less than 90°C. Flexural strengths of dried CFRP and epoxy resin after immersion recovered but were lower than that of virgin CFRP and epoxy resin. Debonding of fiber/resin interface and crack initiation in epoxy resin in distilled water resulted in the strength reduction.


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