Efficient Conversion of Biomass-Derived Levulinic Acid to γ-Valerolactone over Polyoxometalate@Zr-Based Metal–Organic Frameworks: The Synergistic Effect of Bro̷nsted and Lewis Acidic Sites

2021 ◽  
Author(s):  
Jie Li ◽  
Shuaiheng Zhao ◽  
Zhen Li ◽  
Dan Liu ◽  
Yingnan Chi ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Levulinic Acid ◽  
Metal Organic Frameworks ◽  
Efficient Conversion ◽  
Lewis Acidic Sites ◽  
Acidic Sites ◽  
Metal Organic

Exploring the Role of Hexanuclear Clusters as Lewis Acidic Sites in Isostructural Metal–Organic Frameworks

2019 ◽  
Vol 31 (11) ◽  
pp. 4166-4172 ◽  
Author(s):  
Jiafei Lyu ◽  
Xuan Zhang ◽  
Peng Li ◽  
Xingjie Wang ◽  
Cassandra T. Buru ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Hexanuclear Clusters ◽  
Lewis Acidic Sites ◽  
Acidic Sites ◽  
Metal Organic

Ammonia detection by using flexible Lewis acidic sites in luminescent porous frameworks constructed from a bipyridinium derivative

2015 ◽  
Vol 51 (38) ◽  
pp. 8189-8192 ◽  
Author(s):  
Cheng Chen ◽  
Li-Xuan Cai ◽  
Bin Tan ◽  
Ya-Jun Zhang ◽  
Xiao-Dong Yang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Lewis Acidic Sites ◽  
Acidic Sites ◽  
Metal Organic ◽  
Ammonia Detection

A flexible bipyridinium molecule with Lewis acidic sites has been introduced into isoreticular porous metal–organic frameworks to yield anion-tunable luminescence and exhibit different selective response to ammonia.

Synergistic effect of phosphomolybdic acid on rhodium-based metal-organic frameworks for the efficient selective photocatalytic reduction of CO2 to CO

2021 ◽  
Author(s):  
Yurong Shan ◽  
Dexiang Liu ◽  
Chunyan Xu ◽  
Peng Zhan ◽  
Hui Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electronic Structure ◽  
Synergistic Effect ◽  
Metal Organic Frameworks ◽  
Phosphomolybdic Acid ◽  
Photocatalytic Reduction ◽  
Structure And Morphology ◽  
Spherical Structure ◽  
Metal Organic ◽  
Reduction Of Co2

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...

A Facile and Versatile “Click” Approach Toward Multifunctional Ionic Metal–organic Frameworks for Efficient Conversion of CO 2

ChemSusChem ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 2202-2210 ◽  
Author(s):  
Li‐Jiao Zhou ◽  
Wei Sun ◽  
Ning‐Ning Yang ◽  
Peng Li ◽  
Teng Gong ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Efficient Conversion ◽  
Metal Organic

Optimizing zirconium metal–organic frameworks through steric tuning for efficient removal of Cr2O72−

2020 ◽  
Vol 56 (72) ◽  
pp. 10513-10516
Author(s):  
Xiurong Zhang ◽  
Weidong Fan ◽  
Mingyue Fu ◽  
Weifeng Jiang ◽  
Kebin Lu ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Adsorption Capacity ◽  
Functional Groups ◽  
Metal Organic Frameworks ◽  
Adsorption Rate ◽  
Porous Structures ◽  
Efficient Removal ◽  
Metal Organic ◽  
Zirconium Metal

Three Zr-based MOFs are obtained through steric tuning. The synergistic effect between porous structures and functional groups enhanced the adsorption capacity and adsorption rate for Cr2O72−.

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