Synergistic effect of phosphomolybdic acid on rhodium-based metal-organic frameworks for the efficient selective photocatalytic reduction of CO2 to CO

2021 ◽  
Author(s):  
Yurong Shan ◽  
Dexiang Liu ◽  
Chunyan Xu ◽  
Peng Zhan ◽  
Hui Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electronic Structure ◽  
Synergistic Effect ◽  
Metal Organic Frameworks ◽  
Phosphomolybdic Acid ◽  
Photocatalytic Reduction ◽  
Structure And Morphology ◽  
Spherical Structure ◽  
Metal Organic ◽  
Reduction Of Co2

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...

scholarly journals Iron(iii)-bipyridine incorporated metal–organic frameworks for photocatalytic reduction of CO2 with improved performance

2021 ◽  
Vol 50 (1) ◽  
pp. 384-390
Author(s):  
Yuan-Ping Wei ◽  
Sizhuo Yang ◽  
Peng Wang ◽  
Jin-Han Guo ◽  
Jier Huang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Photocatalytic Reduction ◽  
Metal Organic ◽  
Improved Performance ◽  
Reduction Of Co2

A novel MOF UiO-68-Fe-bpy was constructed by post-synthetic modification of a Zr(iv)-based MOF UiO-68-NH2 as a photocatalyst for CO2 reduction.

Systematic variation of the optical bandgap in titanium based isoreticular metal–organic frameworks for photocatalytic reduction of CO2 under blue light

2017 ◽  
Vol 5 (23) ◽  
pp. 11854-11863 ◽  
Author(s):  
Matthew W. Logan ◽  
Suliman Ayad ◽  
Jeremy D. Adamson ◽  
Tristan Dilbeck ◽  
Kenneth Hanson ◽  
...  
Keyword(s):  
Blue Light ◽  
Metal Organic Frameworks ◽  
Optical Bandgap ◽  
Photocatalytic Reduction ◽  
Systematic Variation ◽  
Alkyl Substitution ◽  
Metal Organic ◽  
Reduction Of Co2

N-alkyl substitution–from methyl to heptyl–in isoreticular MIL-125-NH2 MOFs induces a stepwise decrease in the optical bandgap, while increasing CO2 photoreduction efficiencies.

Cobalt-based Metal-organic Frameworks for the Photocatalytic Reduction of Carbon Dioxide

Nanoscale ◽  
2021 ◽  
Author(s):  
Wanxia Zhang ◽  
Ruting Huang ◽  
Xianyang Shi ◽  
Liyan Song
Keyword(s):  
Carbon Dioxide ◽  
Porous Materials ◽  
Coordination Compounds ◽  
Metal Organic Frameworks ◽  
Photocatalytic Reduction ◽  
Metal Centers ◽  
Metal Organic ◽  
Complexation Reactions

Metal-organic frameworks (MOFs) are porous materials composed of metal centers and organic connectors. They are formed by complexation reactions and exhibit characteristics of both polymers and coordination compounds. They display...

The role of leached Zr in the photocatalytic reduction of CO2 to formate by derivatives of UiO-66 metal organic frameworks

2020 ◽  
Vol 49 (15) ◽  
pp. 4751-4757 ◽  
Author(s):  
Moumita Bhattacharya ◽  
Kevin J. Chandler ◽  
Jackson Geary ◽  
Caroline T. Saouma
Keyword(s):  
Metal Organic Frameworks ◽  
Photocatalytic Reduction ◽  
Metal Organic ◽  
Reduction Of Co2 ◽  
Derivatives Of

Photoreduction of CO2 to formate by UiO-66 Zr MOF derivatives is explained by Zr leaching.

scholarly journals Photons to Formate: A Review on Photocatalytic Reduction of CO2 to Formic Acid

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2422
Author(s):  
Hanqing Pan ◽  
Michael D. Heagy
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Atmospheric Carbon Dioxide ◽  
Fossil Fuels ◽  
Photocatalytic Reduction ◽  
Hydrogen Storage Material ◽  
Metal Organic ◽  
Reduction Of Co2 ◽  
Made In ◽  
High Octane

Rising levels of atmospheric carbon dioxide due to the burning and depletion of fossil fuels is continuously raising environmental concerns about global warming and the future of our energy supply. Renewable energy, especially better utilization of solar energy, is a promising method for CO2 conversion and chemical storage. Research in the solar fuels area is focused on designing novel catalysts and developing new conversion pathways. In this review, we focus on the photocatalytic reduction of CO2 primarily in its neutral pH species of carbonate to formate. The first two-electron photoproduct of carbon dioxide, a case for formate (or formic acid) is made in this review based on its value as; an important chemical feedstock, a hydrogen storage material, an intermediate to methanol, a high-octane fuel and broad application in fuel cells. This review focuses specifically on the following photocatalysts: semiconductors, phthalocyanines as photosensitizers and membrane devices and metal-organic frameworks.

Metal–organic frameworks (ZIF-67) as efficient cocatalysts for photocatalytic reduction of CO2: the role of the morphology effect

2018 ◽  
Vol 6 (11) ◽  
pp. 4768-4775 ◽  
Author(s):  
Mang Wang ◽  
Jinxuan Liu ◽  
Chunmei Guo ◽  
Xiaosu Gao ◽  
Chenghuan Gong ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photocatalytic Activity ◽  
Metal Organic Frameworks ◽  
Photocatalytic Reduction ◽  
Two Dimensional ◽  
Metal Organic ◽  
Morphology Effect ◽  
Reduction Of Co2 ◽  
Adsorption Capability

The two-dimensional ZIF-67 with a leaf-like morphology exhibited the best photocatalytic activity and stability due to the highest CO2 adsorption capability and efficient electron transfer from the excited [Ru(bpy)3]2+ to ZIF-67.

scholarly journals Electronic structure of porphyrin-based metal–organic frameworks and their suitability for solar fuel production photocatalysis

2015 ◽  
Vol 3 (46) ◽  
pp. 23458-23465 ◽  
Author(s):  
Said Hamad ◽  
Norge C. Hernandez ◽  
Alex Aziz ◽  
A. Rabdel Ruiz-Salvador ◽  
Sofia Calero ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Density Functional Theory ◽  
Electronic Structure ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Density Functional Theory Calculations ◽  
Carbon Dioxide Reduction ◽  
Fuel Production ◽  
Functional Theory ◽  
Metal Organic

Density functional theory calculations reveal that the electronic structure of a family of porphyrin-based metal–organic frameworks is suitable for the photocatalysis of water splitting and carbon dioxide reduction reactions.

Single- and mixed-metal-organic framework photocatalysts for carbon dioxide reduction

2021 ◽  
Author(s):  
Xiao-Yao Dao ◽  
Wei-Yin Sun
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emission ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Value Added ◽  
Carbon Dioxide Reduction ◽  
Photocatalytic Reduction ◽  
Metal Organic ◽  
Carbon Dioxide Co2 ◽  
Working Out

Photocatalytic reduction of carbon dioxide (CO2) into high value-added chemical fuels is deemed as a charming way for working out energy dilemma and ameliorate the extreme CO2 emission. Metal-organic frameworks...

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