scholarly journals Editorial: Guidelines for the Measurement of Solid–Liquid Solubility Data at Atmospheric Pressure

2019 ◽  
Vol 64 (2) ◽  
pp. 381-385 ◽  
Author(s):  
Erich Königsberger
2015 ◽  
Vol 37 (5-6) ◽  

In the 1970s, IUPAC’s Solubility Data Commission (now the Subcommittee on Solubility and Equilibrium Data) embarked on a project to compile and critically evaluate experimental data for solubility in systems of scientific and practical interest. The first volume in the IUPAC Solubility Data Series, covering the solubility of helium and neon in liquid solvents, was published in 1979. Subsequent years saw many volumes on gas-liquid, liquid-liquid, and solid-liquid solubilities. These volumes are an invaluable scientific resource.


2010 ◽  
Vol 82 (5) ◽  
pp. 1137-1159 ◽  
Author(s):  
Heinz Gamsjäger ◽  
John W. Lorimer ◽  
Mark Salomon ◽  
David G. Shaw ◽  
Reginald P. T. Tomkins

The IUPAC-NIST Solubility Data Series (SDS) is an ongoing project that provides comprehensive reviews of published data for solubilities of gases, liquids, and solids in liquids or solids. Data are compiled in a uniform format, evaluated, and, where data from independent sources agree sufficiently, recommended values are proposed. This paper is a guide to the SDS and is intended for the benefit of both those who use the SDS as a source of critically evaluated solubility data and who prepare compilations and evaluations for future volumes. A major portion of this paper presents terminology and nomenclature currently recommended by IUPAC and other international bodies and relates these to obsolete forms that appear in the older solubility literature. In addition, this paper presents a detailed guide to the criteria and procedures used in data compilation, evaluation, and presentation and considers special features of solubility in gas + liquid, liquid + liquid, and solid + liquid systems. In the past, much of this information was included in introductory sections of individual volumes of the SDS. However, to eliminate repetitive publication, this information has been collected, updated, and expanded for separate publication here.


2003 ◽  
Vol 81 (5) ◽  
pp. 385-391 ◽  
Author(s):  
F Blanchard ◽  
B Carré ◽  
F Bonhomme ◽  
P Biensan ◽  
D Lemordant

The solubility of carbon dioxide in γ-butyrolactone (BL), caprolactone (CL), propylene carbonate (PC), ethylene carbonate (EC), dimethylcarbonate (DMC), diethylcarbonate (DEC), and mixtures of these components has been determined at temperatures from 275 to 333 K at atmospheric pressure. The Henry's law constant (kH) for the dissolution of CO2 in these solvents has been deduced from the solubility data. The value of kH increases in the following order: DEC < DMC < PC < CL < BL < EC, which is identical to the order of the Hildebrand parameters (δ) of the corresponding solvents. The accuracy of classical theories for predicting gas solubilities in liquids has been examined. The best results are given by the Vilcu–Perisamu equation, which is derived from the Scatchard–Hildebrand theory but takes into account the polarizability of the solute and the permittivity of the solvent. A modified form of the Prausnitz and Shair equation is proposed to estimate the solubility of nonpolar molecules in strongly dipolar solvents. This equation fits the experimental data with improved precision.Key words: alkylcarbonate, lactone, carbon dioxide, liquid–gas equilibrium, Henry's law, Hildebrand parameter.


Sign in / Sign up

Export Citation Format

Share Document