scholarly journals Velocity-Map Imaging and Magnetic-Bottle Photoelectron Spectroscopy of [SeCCH]−: Electronic Properties and Spin–Orbit Splitting

2020 ◽  
Vol 124 (16) ◽  
pp. 3214-3219
Author(s):  
Qinqin Yuan ◽  
Wenjin Cao ◽  
Marc Hetzert ◽  
Uwe Ruschewitz ◽  
Xue-Bin Wang

1996 ◽  
Vol 16 (3) ◽  
pp. 151-156 ◽  
Author(s):  
Hiroshi Matsui ◽  
Yi-Fei Zhu ◽  
Edward R. Grant

Using techniques of delayed pulsed-field ionization zero-kinetic-energy (ZEKE) photoelectron spectroscopy, we have resolved spin-orbit structure in the rotational profile of the origin band in the non-resonant two-photon threshold photoionization of propyne. Both the rotational and spin-orbit characteristics of this band are well-simulated by a simple model that assumes the spin-orbit splitting of acetylene cation in combination with the rotational constants of the neutral propyne ground state. This result, combined with very little evidence for photoionizing transitions terminating on vibronically excited states, suggests that the structure of the propyne cation structure is very close to that of the neutral ground state and very little altered by Jahn-Teller distortion.



RSC Advances ◽  
2017 ◽  
Vol 7 (19) ◽  
pp. 11761-11767 ◽  
Author(s):  
Tongwei Li ◽  
Xiangying Su ◽  
Haisheng Li ◽  
Weiwei Ju

Electronic properties and spin–orbit (SO) splitting of silicene adsorbed with Cu, Ag, Au and Pb atoms at different coverages are investigated by means of first-principles calculations.



1995 ◽  
Vol 50 (11) ◽  
pp. 1041-1044 ◽  
Author(s):  
J. Schiedt ◽  
R. Weinkauf

Abstract We could resolve the spin-orbit splitting of 160 ± 4 cm-1 in the 2II ground state of O2- anions by high resolution photodetachment photoelectron spectroscopy. The observed splitting is in good agreement with the theoretically derived value. Our directly measured electron affinity of O 2 is 450 ± 2 meV and deviates within experiment errors from previous values. kHz repetition rate was applied to avoid space charge and improve electron energy resolution in a time-of-flight electron energy analyzer.





2014 ◽  
Vol 89 (8) ◽  
Author(s):  
Fabrizio Nichele ◽  
Atindra Nath Pal ◽  
Roland Winkler ◽  
Christian Gerl ◽  
Werner Wegscheider ◽  
...  




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