Photoelectron Spectroscopy of the Water Dimer Reveals Unpredicted Vibrational Structure

2021 ◽  
Author(s):  
Sebastian Hartweg ◽  
Gustavo A. Garcia ◽  
Laurent Nahon
Keyword(s):  
Photoelectron Spectroscopy ◽  
Vibrational Structure ◽  
Water Dimer

A Discussion on photoelectron spectroscopy - Franck-Condon factors and autoionization in the photoelectron spectra of diatomic molecules

1970 ◽  
Vol 268 (1184) ◽  
pp. 159-162 ◽  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Photoionization Cross Section ◽  
Resonance Wavelength ◽  
Exciting Radiation ◽  
Vibrational Structure ◽  
Photoelectron Spectra ◽  
Condon Factors ◽  
Franck Condon ◽  
Characteristic Manner ◽  
Good Agreement

Distributions of calculated Franck-Condon factors for autoionizing transitions are used to illustrate the way in which the vibrational structure of the photoelectron spectrum may be extended in a characteristic manner when the wavelength of the exciting radiation coincides with a resonance in the photoionization cross section of a diatomic gas. The calculations are found to be in good agreement with resonance wavelength photoelectron spectra from O2.

A Discussion on photoelectron spectroscopy - The photoelectron spectra of isocyanic acid and related compounds

1970 ◽  
Vol 268 (1184) ◽  
pp. 87-96 ◽  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Vibrational Structure ◽  
Photoelectron Spectra ◽  
Isocyanic Acid ◽  
Hydrazoic Acid ◽  
Methyl Isocyanate ◽  
Methyl Isothiocyanate ◽  
Complete Identification ◽  
Related Compounds ◽  
Clear Relation

Photoelectron spectra of isocyanic acid, isothiocyanic acid and hydrazoic acid excited by helium resonance radiation are presented. A complete identification of the orbitals from which electrons are ejected has been obtained by comparison with the photoelectron spectra of carbon dioxide, carbon oxysulphide and nitrous oxide, by consideration of the vibrational structure and intensities of the bands and by comparison with the photoelectron spectra of methyl isocyanate and methyl isothiocyanate. A clear relation is found between the photoelectron spectra and the bond angles in the neutral molecules.

Vibrational structure of the N+2 ground state observed by threshold photoelectron spectroscopy

1996 ◽  
Vol 104 (23) ◽  
pp. 9357-9361 ◽  
Author(s):  
Y. Morioka ◽  
Y. Lu ◽  
T. Matsui ◽  
T. Tanaka ◽  
H. Yoshii ◽  
...  
Keyword(s):  
Ground State ◽  
Photoelectron Spectroscopy ◽  
Vibrational Structure

Probing the electronic and vibrational structure of Au2Al2− and Au2Al2 using photoelectron spectroscopy and high resolution photoelectron imaging

2014 ◽  
Vol 141 (22) ◽  
pp. 224309 ◽  
Author(s):  
Gary V. Lopez ◽  
Joseph Czekner ◽  
Tian Jian ◽  
Wei-Li Li ◽  
Zheng Yang ◽  
...  
Keyword(s):  
High Resolution ◽  
Photoelectron Spectroscopy ◽  
Vibrational Structure ◽  
Photoelectron Imaging

Vibrational structure of the chloromethane series, CH4−nCln, studied by core photoelectron spectroscopy and ab initio calculations

1999 ◽  
Vol 110 (12) ◽  
pp. 5806-5813 ◽  
Author(s):  
S. Sundin ◽  
L. J. Saethre ◽  
S. L. Sorensen ◽  
A. Ausmees ◽  
S. Svensson
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Photoelectron Spectroscopy ◽  
Vibrational Structure
Sign in / Sign up

Export Citation Format

Share Document