Free-Energy-Gap Law for Ultrafast Charge Recombination of Ion Pairs Formed by Intramolecular Photoinduced Electron Transfer

2017 ◽  
Vol 121 (3) ◽  
pp. 589-598 ◽  
Author(s):  
Alexey E. Nazarov ◽  
Roman Malykhin ◽  
Anatoly I. Ivanov
Keyword(s):  
Electron Transfer ◽  
Free Energy ◽  
Photoinduced Electron Transfer ◽  
Energy Gap ◽  
Ion Pairs ◽  
Charge Recombination ◽  
Energy Gap Law

Photoinduced electron transfer in wild type and mutated flavodoxin from Desulfovibrio vulgaris, strain Miyazaki F.: Energy gap law

2011 ◽  
Vol 219 (1) ◽  
pp. 32-41 ◽  
Author(s):  
Kiattisak Lugsanangarm ◽  
Somsak Pianwanit ◽  
Sirirat Kokpol ◽  
Fumio Tanaka ◽  
Haik Chosrowjan ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Energy Gap ◽  
Desulfovibrio Vulgaris ◽  
Wild Type ◽  
Energy Gap Law

scholarly journals Electronic and spatial control over the formation of transient ion pairs during photoinduced electron transfer between proflavine–amine systems in a subpicosecond time regime

RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15149-15157 ◽  
Author(s):  
Chaitrali Sengupta ◽  
Piyali Mitra ◽  
Banabithi Koley Seth ◽  
Debabrata Mandal ◽  
Samita Basu
Keyword(s):  
Physical Chemistry ◽  
Electron Transfer ◽  
Free Energy ◽  
Photoinduced Electron Transfer ◽  
Ion Pairs ◽  
Spatial Control ◽  
Rate Of Reaction ◽  
Reaction Free Energy ◽  
Time Regime

Probing photoinduced electron transfer (PET) in solution in terms of rate of reaction and reaction free energy is a great challenge in physical chemistry.

Nonequilibrium Phenomena in Charge Recombination of Excited Donor−Acceptor Complexes and Free Energy Gap Law

2010 ◽  
Vol 114 (50) ◽  
pp. 12998-13004 ◽  
Author(s):  
Vladislav V. Yudanov ◽  
Valentina A. Mikhailova ◽  
Anatoly I. Ivanov
Keyword(s):  
Free Energy ◽  
Energy Gap ◽  
Charge Recombination ◽  
Nonequilibrium Phenomena ◽  
Energy Gap Law ◽  
Donor Acceptor

Photoinduced electron-transfer reactions of porphyrin heteroaggregates: energy gap dependence of an intradimer charge recombination process

1992 ◽  
Vol 96 (2) ◽  
pp. 503-506 ◽  
Author(s):  
Hiroshi Segawa ◽  
Chie Takehara ◽  
Kenichi Honda ◽  
Takeo Shimidzu ◽  
Tsuyoshi Asahi ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Energy Gap ◽  
Charge Recombination ◽  
Recombination Process ◽  
Transfer Reactions ◽  
Electron Transfer Reactions

scholarly journals Equivalence between inverted regions of the energy gap law and inverted regions of donor–acceptor distances in photoinduced electron transfer processes in flavoproteins

RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8821-8832
Author(s):  
Nadtanet Nunthaboot ◽  
Seiji Taniguchi ◽  
Haik Chosrowjan ◽  
Fumio Tanaka
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Energy Gap ◽  
Transfer Processes ◽  
Energy Gap Law ◽  
Donor Acceptor ◽  
Electron Transfer Processes

Relationship between EXDL and SEGL.

scholarly journals The effect of solvent relaxation time constants on free energy gap law for ultrafast charge recombination following photoinduced charge separation

2018 ◽  
Vol 17 (5) ◽  
pp. 607-616 ◽  
Author(s):  
Valentina A. Mikhailova ◽  
Roman E. Malykhin ◽  
Anatoly I. Ivanov
Keyword(s):  
Free Energy ◽  
Charge Separation ◽  
Energy Gap ◽  
Charge Recombination ◽  
Solvent Relaxation ◽  
Equilibrium Mode ◽  
Energy Gap Law ◽  
Photoinduced Charge Separation ◽  
Relaxation Time Constants ◽  
Photoinduced Charge

Ultrafast low exergonic charge recombination following photoinduced charge separation proceeds in a non-equilibrium mode and its rate constant is nearly independent of the free energy gap.

Diffusional distortion of the free‐energy gap law

1995 ◽  
Vol 103 (18) ◽  
pp. 7927-7933 ◽  
Author(s):  
A. I. Burshtein
Keyword(s):  
Free Energy ◽  
Energy Gap ◽  
Energy Gap Law

Solvent effect on the electron transfer rate and the energy gap law

1994 ◽  
Author(s):  
M. Tachiya ◽  
Maria Hilczer
Keyword(s):  
Electron Transfer ◽  
Solvent Effect ◽  
Transfer Rate ◽  
Energy Gap ◽  
Electron Transfer Rate ◽  
Energy Gap Law
Sign in / Sign up

Export Citation Format

Share Document