Transition-Metal-Incorporated Aluminum Oxide Thin Films: Toward Electronic Structure Design in Amorphous Mixed-Metal Oxides

2018 ◽  
Vol 122 (25) ◽  
pp. 13691-13704 ◽  
Author(s):  
Lisa J. Enman ◽  
Matthew G. Kast ◽  
Elizabeth A. Cochran ◽  
Erica Pledger ◽  
Michaela Burke Stevens ◽  
...  
Keyword(s):  
Thin Films ◽  
Electronic Structure ◽  
Transition Metal ◽  
Aluminum Oxide ◽  
Metal Oxides ◽  
Structure Design ◽  
Mixed Metal Oxides ◽  
Oxide Thin Films ◽  
Mixed Metal

Selective oxidation of ammonia to nitrogen on transition metal containing mixed metal oxides

2005 ◽  
Vol 58 (3-4) ◽  
pp. 235-244 ◽  
Author(s):  
Lucjan Chmielarz ◽  
Piotr Kuśtrowski ◽  
Alicja Rafalska-Łasocha ◽  
Roman Dziembaj
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Selective Oxidation ◽  
Mixed Metal Oxides ◽  
Mixed Metal ◽  
Oxidation Of Ammonia

Ellipsometric analysis of mixed metal oxides thin films

2008 ◽  
Vol 517 (1) ◽  
pp. 453-455 ◽  
Author(s):  
O. Buiu ◽  
W. Davey ◽  
Y. Lu ◽  
I.Z. Mitrovic ◽  
S. Hall
Keyword(s):  
Thin Films ◽  
Metal Oxides ◽  
Mixed Metal Oxides ◽  
Mixed Metal

Understanding Surface Reactivity of Amorphous Transition-Metal-Incorporated Aluminum Oxide Thin Films

2019 ◽  
Vol 123 (44) ◽  
pp. 27048-27054
Author(s):  
Kelsey A. Stoerzinger ◽  
Lisa J. Enman ◽  
Elizabeth A. Cochran ◽  
J. Trey Diulus ◽  
Ryan T. Frederick ◽  
...  
Keyword(s):  
Thin Films ◽  
Transition Metal ◽  
Aluminum Oxide ◽  
Surface Reactivity ◽  
Oxide Thin Films

Early Transition Metal Oxides and a Pinch of Salt: New Synthetic Routes to Titanates and Niobates

1996 ◽  
Vol 453 ◽  
Author(s):  
M. J. Geselbracht ◽  
R. J. Scarola ◽  
D. Ingram ◽  
C. Green ◽  
J. H. Caldwell
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Molten Salts ◽  
Calcium Titanate ◽  
Mixed Metal Oxides ◽  
Mixed Metal ◽  
Early Transition Metal ◽  
Synthetic Routes ◽  
Early Transition

AbstractMolten salts have traditionally been used as recrystallizing solvents for the crystal growth of mixed metal oxides. In recent years, many examples of the direct preparation of mixed metal oxides from molten salt solutions have been reported. We have been exploring the use of chloride melts as a reaction media to prepare complex early transition metal oxides. Specific examples of new synthetic routes to interesting titanates and niobates will be presented. In one case, we have prepared a series of layered niobate perovskite solid acids from molten salts at temperatures well below those traditionally used in solid state syntheses. In the second case, we have discovered a new synthetic route to a poorly characterized reduced calcium titanate that is otherwise very difficult to make. The synthesis and characterization of these two classes of compounds will be described.

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