In Situ Formation of Polycyclic Aromatic Hydrocarbons as an Artificial Hybrid Layer for Lithium Metal Anodes

Nano Letters ◽  
2021 ◽  
Author(s):  
Shaozhong Chang ◽  
Xin Jin ◽  
Qiya He ◽  
Tongchao Liu ◽  
Jiabin Fang ◽  
...  
2017 ◽  
Vol 29 (8) ◽  
pp. 3572-3579 ◽  
Author(s):  
Haiping Wu ◽  
Yue Cao ◽  
Linxiao Geng ◽  
Chao Wang

Nanoscale ◽  
2021 ◽  
Author(s):  
Huai Jiang ◽  
Qingyuan Dong ◽  
Maohui Bai ◽  
Furong Qin ◽  
Maoyi Yi ◽  
...  

Lithium (Li) metal is widely considered as the most promising anode material because of ultrahigh specific energy. However, obvious volume change and uncontrollable dendrite growth hinder its commercial application. Herein,...


2019 ◽  
Author(s):  
Thomas Delouche ◽  
Antoine Vacher ◽  
Elsa Caytan ◽  
Thierry Roisnel ◽  
Boris Le Guennic ◽  
...  

In this communication, we report the straightforward<br>synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach.<br>Finally, (spectro)-electrochemical studies prove that these<br>compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical.


2019 ◽  
Vol 7 (44) ◽  
pp. 25415-25422 ◽  
Author(s):  
Lan Wu ◽  
Guang He ◽  
Yi Ding

In situ fabrication of Li–Al protection layer for lithium metal anodes has been achieved with ultrathin Al foil. The hybrid Li–Al/Li anodes demonstrate excellent cycling stability at plating current and capacity up to 8 mA cm−2 and 4 mA h cm−2.


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