Palladium-Catalyzed Stereoselective C−F Bond Vinylation and Allylation of Tetrasubstituted gem-Difluoroalkenes via Stille Coupling: Synthesis of Monofluorinated 1,3- and 1,4-Dienes

2021 ◽  
Author(s):  
Min Li ◽  
Yanhui Wang ◽  
Gavin Chit Tsui
Keyword(s):  
Stille Coupling ◽  
Palladium Catalyzed

Ligand-Free and Solvent-Free Synthesis of 1,3-Disubstituted Naphthalenes through Stille Coupling

Synlett ◽  
2020 ◽  
Vol 31 (09) ◽  
pp. 903-906
Author(s):  
Taoufik Rohand ◽  
Sanae Sbi ◽  
Victor Mkpenie ◽  
Kiyoshi Tanemura
Keyword(s):  
Functional Groups ◽  
Acetyl Chloride ◽  
Stille Coupling ◽  
Mechanistic Studies ◽  
Major Step ◽  
Mild Conditions ◽  
Synthetic Strategy ◽  
Ligand Free ◽  
Palladium Catalyzed ◽  
Solvent Free Synthesis

A variety of 1,3-disubstituted naphthalenes have been prepared by palladium-catalyzed annulation of (o-ethynylphenyl)acetyl chloride with design of a new synthetic strategy by Stille coupling using functionalized organostannanes. The method affords excellent yields of the substituted naphthalenes and accommodates a wide variety of functional groups under mild conditions. Mechanistic studies show intramolecular cyclization as a major step following C–C bond coupling.

Palladium-Catalyzed Stille Coupling for the Preparation of Ferrocenyl Thiophene Derivatives

2000 ◽  
Vol 30 (13) ◽  
pp. 2281-2285 ◽  
Author(s):  
Chao-Min Liu ◽  
Sheng-Jun Luo ◽  
Yong-Min Liang ◽  
Yong-Xiang Ma
Keyword(s):  
Stille Coupling ◽  
Palladium Catalyzed ◽  
Thiophene Derivatives

Palladium chemistry in recent porphyrin research

2004 ◽  
Vol 08 (01) ◽  
pp. 93-102 ◽  
Author(s):  
Jun-ichiro Setsune
Keyword(s):  
Supramolecular Assembly ◽  
Molecular Size ◽  
Sonogashira Coupling ◽  
Stille Coupling ◽  
Heck Reactions ◽  
Nano Scale ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Palladium Chemistry ◽  
Catalyzed Reactions

Palladium-catalyzed reactions such as Sonogashira coupling, Suzuki coupling, Stille coupling, Heck reactions, and Glaser-Hey oxidation were used to construct porphyrin modules of nano-scale molecular size in recent years. Recent developments in the supramolecular assembly of porphyrins and Pd (II) and in the organopalladium complexes of various porphyrins are also summarized.

Room-Temperature Stille Coupling of Tetraarylstannanes via Palladium-Catalyzed C-H Activation

Synlett ◽  
2012 ◽  
Vol 23 (13) ◽  
pp. 1941-1946 ◽  
Author(s):  
Dong Xue ◽  
Jianliang Xiao ◽  
Jing Li ◽  
Yu-Xia Liu ◽  
Wen-Yong Han ◽  
...  
Keyword(s):  
Room Temperature ◽  
Stille Coupling ◽  
Palladium Catalyzed

Highly selective palladium-catalyzed Stille coupling reaction toward chlorine-containing NIR electroluminescent polymers

2015 ◽  
Vol 3 (28) ◽  
pp. 7463-7468 ◽  
Author(s):  
Yubao Zhang ◽  
Xiang Gao ◽  
Junli Li ◽  
Guoli Tu
Keyword(s):  
Conjugated Polymers ◽  
Coupling Reaction ◽  
Stille Coupling ◽  
Palladium Catalyzed ◽  
Nir Emission ◽  
Stille Coupling Reaction ◽  
Electroluminescent Polymers

Chlorine-containing conjugated polymers were obtained by the optimized Stille coupling reaction; non-doped PLEDs of the polymers exhibited NIR emission.

ChemInform Abstract: Palladium-Catalyzed Stille Coupling for the Preparation of Ferrocenyl Thiophene Derivatives.

ChemInform ◽  
2000 ◽  
Vol 31 (41) ◽  
pp. no-no
Author(s):  
Chao-Min Liu ◽  
Sheng-Jun Luo ◽  
Yong-Min Liang ◽  
Yong-Xiang Ma
Keyword(s):  
Stille Coupling ◽  
Palladium Catalyzed ◽  
Thiophene Derivatives
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