Relay Catalysis: Manganese(III) Phosphate Catalyzed Asymmetric Addition of β-Dicarbonyls to ortho-Quinone Methides Generated by Catalytic Aerobic Oxidation

2017 ◽  
Vol 19 (17) ◽  
pp. 4588-4591 ◽  
Author(s):  
Konrad Gebauer ◽  
Franziska Reuß ◽  
Matthias Spanka ◽  
Christoph Schneider
Keyword(s):  
Aerobic Oxidation ◽  
Quinone Methides ◽  
Asymmetric Addition

ChemInform Abstract: Catalytic Asymmetric Addition of Meldrum′s Acid, Malononitrile, and 1,3-Dicarbonyls to ortho-Quinone Methides Generated in situ under Basic Conditions.

ChemInform ◽  
2015 ◽  
Vol 46 (35) ◽  
pp. no-no
Author(s):  
Lorenzo Caruana ◽  
Martina Mondatori ◽  
Vasco Corti ◽  
Sara Morales ◽  
Andrea Mazzanti ◽  
...  
Keyword(s):  
Quinone Methides ◽  
Asymmetric Addition ◽  
Catalytic Asymmetric

Chiral phosphoric acid catalyzed asymmetric addition of naphthols to para-quinone methides

2016 ◽  
Vol 14 (24) ◽  
pp. 5751-5754 ◽  
Author(s):  
Yuk Fai Wong ◽  
Zhaobin Wang ◽  
Jianwei Sun
Keyword(s):  
Phosphoric Acid ◽  
Quinone Methides ◽  
Asymmetric Addition ◽  
Chiral Phosphoric Acid ◽  
Acid Catalyzed

An asymmetric addition of naphthols to in situ generated para-quinone methides catalyzed by a chiral phosphoric acid is described.

scholarly journals Quaternary β2,2-amino acid derivatives by asymmetric addition of isoxazolidin-5-ones to para-quinone methides

2020 ◽  
Vol 56 (4) ◽  
pp. 579-582 ◽  
Author(s):  
Andreas Eitzinger ◽  
Michael Winter ◽  
Johannes Schörgenhumer ◽  
Mario Waser
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Phase Transfer ◽  
Phase Transfer Catalyst ◽  
Amino Acid Derivatives ◽  
Quinone Methides ◽  
Chiral Phase ◽  
Asymmetric Addition

Novel densely functionalized β2,2-amino acids were obtained in almost enantiopure form using down to 20 ppm of a chiral phase-transfer catalyst.

Catalytic Asymmetric Addition of Meldrum’s Acid, Malononitrile, and 1,3-Dicarbonyls toortho-Quinone Methides Generated In Situ Under Basic Conditions

2015 ◽  
Vol 21 (16) ◽  
pp. 6037-6041 ◽  
Author(s):  
Lorenzo Caruana ◽  
Martina Mondatori ◽  
Vasco Corti ◽  
Sara Morales ◽  
Andrea Mazzanti ◽  
...  
Keyword(s):  
Meldrum's Acid ◽  
Quinone Methides ◽  
Meldrum’S Acid ◽  
Asymmetric Addition ◽  
Catalytic Asymmetric

Organocatalytic asymmetric addition of thioglycolates to o-quinone methides: a route to 5-substituted-5H-benzoxathiepine-2(3H)-ones

2020 ◽  
Vol 18 (15) ◽  
pp. 2828-2833
Author(s):  
Chandan Gharui ◽  
Satya Prakash ◽  
Deepak Chopra ◽  
Subhas Chandra Pan
Keyword(s):  
Enantioselective Synthesis ◽  
Quinone Methides ◽  
Asymmetric Addition

The first enantioselective synthesis of 5-substituted-5H-benzoxathiepine-2(3H)-ones via organocatalytic asymmetric addition of thioglycolates to o-quinone methides followed by cyclization.

The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

Oxidase Catalysis via an Aerobically Generated Dess-Martin Periodinane Analogue

2018 ◽  
Author(s):  
Asim Maity ◽  
Sung-Min Hyun ◽  
Alan Wortman ◽  
David Powers
Keyword(s):  
Chemical Synthesis ◽  
Aerobic Oxidation ◽  
Substrate Oxidation ◽  
Oxidation Catalysis ◽  
Hypervalent Iodine ◽  
Oxidation Reactions ◽  
Broad Array ◽  
Oxidation Chemistry ◽  
Reactive Oxidants

<p>Hypervalent iodine(V) reagents, such as Dess-Martin periodinane (DMP) and 2-iodoxybenzoic acid (IBX), are broadly useful oxidants in chemical synthesis. Development of strategies to access these reagents from O2 would immediately enable use of O2 as a terminal oxidant in a broad array of substrate oxidation reactions. Recently we disclosed the aerobic synthesis of I(III) reagents by intercepting reactive oxidants generated during aldehyde autoxidation. Here, we couple aerobic oxidation of iodobenzenes with disproportionation of the initially generated I(III) compounds to generate I(V) reagents. The aerobically generated I(V) reagents exhibit substrate oxidation chemistry analogous to that of DMP. Further, the developed aerobic generation of I(V) has enabled the first application of I(V) intermediates in aerobic oxidation catalysis.</p>

Recent Development in Aerobic Oxidation of Amines

2012 ◽  
Vol 9 (3) ◽  
pp. 319-340
Author(s):  
Bo-Tao Xin ◽  
Qing-Fa Zhou ◽  
Tao Lu
Keyword(s):  
Aerobic Oxidation
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