Ionic Liquid Electrolyte-Based Switchable Mirror with Fast Response and Improved Durability

Author(s):  
Xiao Hou ◽  
Zhenyong Wang ◽  
Ji Pan ◽  
Feng Yan
2020 ◽  
Author(s):  
Urbi Pal ◽  
Fangfang Chen ◽  
Derick Gyabang ◽  
Thushan Pathirana ◽  
Binayak Roy ◽  
...  

We explore a novel ether aided superconcentrated ionic liquid electrolyte; a combination of ionic liquid, <i>N</i>-propyl-<i>N</i>-methylpyrrolidinium bis(fluorosulfonyl)imide (C<sub>3</sub>mpyrFSI) and ether solvent, <i>1,2</i> dimethoxy ethane (DME) with 3.2 mol/kg LiFSI salt, which offers an alternative ion-transport mechanism and improves the overall fluidity of the electrolyte. The molecular dynamics (MD) study reveals that the coordination environment of lithium in the ether aided ionic liquid system offers a coexistence of both the ether DME and FSI anion simultaneously and the absence of ‘free’, uncoordinated DME solvent. These structures lead to very fast kinetics and improved current density for lithium deposition-dissolution processes. Hence the electrolyte is used in a lithium metal battery against a high mass loading (~12 mg/cm<sup>2</sup>) LFP cathode which was cycled at a relatively high current rate of 1mA/cm<sup>2</sup> for 350 cycles without capacity fading and offered an overall coulombic efficiency of >99.8 %. Additionally, the rate performance demonstrated that this electrolyte is capable of passing current density as high as 7mA/cm<sup>2</sup> without any electrolytic decomposition and offers a superior capacity retention. We have also demonstrated an ‘anode free’ LFP-Cu cell which was cycled over 50 cycles and achieved an average coulombic efficiency of 98.74%. The coordination chemistry and (electro)chemical understanding as well as the excellent cycling stability collectively leads toward a breakthrough in realizing the practical applicability of this ether aided ionic liquid electrolytes in lithium metal battery applications, while delivering high energy density in a prototype cell.


Ionics ◽  
2019 ◽  
Vol 25 (9) ◽  
pp. 4351-4360 ◽  
Author(s):  
Zhongliang Yu ◽  
Jiahe Zhang ◽  
Chunxian Xing ◽  
Lei Hu ◽  
Lili Wang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (43) ◽  
pp. 33855-33862 ◽  
Author(s):  
Molang Cai ◽  
Xu Pan ◽  
Weiqing Liu ◽  
John Bell ◽  
Songyuan Dai

DMImBS is used as a novel additive in dye-sensitized solar cells to restrain the electron recombination and intercalation of Li+.


2018 ◽  
Vol 5 (10) ◽  
pp. 1340-1344 ◽  
Author(s):  
Shubham Kaushik ◽  
Jinkwang Hwang ◽  
Kazuhiko Matsumoto ◽  
Yuta Sato ◽  
Rika Hagiwara

2006 ◽  
Vol 51 (12) ◽  
pp. 2471-2476 ◽  
Author(s):  
Paul S. Murray ◽  
Stephen F. Ralph ◽  
Chee O. Too ◽  
Gordon G. Wallace

2014 ◽  
Vol 2 (47) ◽  
pp. 20237-20242 ◽  
Author(s):  
D. Gelman ◽  
B. Shvartsev ◽  
Y. Ein-Eli

This study presents a novel non-aqueous Al–air battery utilizing 1-ethyl-3-methylimidazolium oligo-fluoro-hydrogenate room temperature ionic liquid. The Al–air-RTIL system can sustain current densities up to 1.5 mA cm−2, producing capacities above 140 mA h cm−2, thus utilizing above 70% of the theoretical Al capacity.


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