Online Monitoring of Transition-Metal Dissolution from a High-Ni-Content Cathode Material

Author(s):  
Susanne J. Wachs ◽  
Christopher Behling ◽  
Johanna Ranninger ◽  
Jonas Möller ◽  
Karl J. J. Mayrhofer ◽  
...  
2011 ◽  
Vol 04 (03) ◽  
pp. 299-303 ◽  
Author(s):  
ZHUO TAN ◽  
PING GAO ◽  
FUQUAN CHENG ◽  
HONGJUN LUO ◽  
JITAO CHEN ◽  
...  

A multicomponent olivine cathode material, LiMn0.4Fe0.6PO4 , was synthesized via a novel coprecipitation method of the mixed transition metal oxalate. X-ray diffraction patterns indicate that carbon-coated LiMn0.4Fe0.6PO4 has been prepared successfully and that LiMn0.4Fe0.6PO4/C is crystallized in an orthorhombic structure without noticeable impurity. Homogeneous distribution of Mn and Fe in LiMn0.4Fe0.6PO4/C can be observed from the scanning electron microscopy (SEM) and the corresponding energy dispersive X-ray spectrometry (EDS) analysis. Hence, the electrochemical activity of each transition metal in the olivine synthesized via coprecipitation method was enhanced remarkably, as indicated by the galvanostatic charge/discharge measurement. The synthesized LiMn0.4Fe0.6PO4/C exhibits a high capacity of 158.6 ± 3 mAhg-1 at 0.1 C, delivering an excellent rate capability of 122.6 ± 3 mAhg-1 at 10 C and 114.9 ± 3 mAhg-1 at 20 C.


Batteries ◽  
2022 ◽  
Vol 8 (1) ◽  
pp. 4
Author(s):  
Shofirul Sholikhatun Nisa ◽  
Mintarsih Rahmawati ◽  
Cornelius Satria Yudha ◽  
Hanida Nilasary ◽  
Hartoto Nursukatmo ◽  
...  

Li-ion batteries as a support for future transportation have the advantages of high storage capacity, a long life cycle, and the fact that they are less dangerous than current battery materials. Li-ion battery components, especially the cathode, are the intercalation places for lithium, which plays an important role in battery performance. This study aims to obtain the LiNixMnyCozO2 (NMC) cathode material using a simple flash coprecipitation method. As precipitation agents and pH regulators, oxalic acid and ammonia are widely available and inexpensive. The composition of the NMC mole ratio was varied, with values of 333, 424, 442, 523, 532, 622, and 811. As a comprehensive study of NMC, lithium transition-metal oxide (LMO, LCO, and LNO) is also provided. The crystal structure, functional groups, morphology, elemental composition and material behavior of the particles were all investigated during the heating process. The galvanostatic charge–discharge analysis was tested with cylindrical cells and using mesocarbon microbeads/graphite as the anode. Cells were tested at 2.7–4.25 V at 0.5 C. Based on the analysis results, NMC with a mole ratio of 622 showed the best characteristicd and electrochemical performance. After 100 cycles, the discharged capacity reaches 153.60 mAh/g with 70.9% capacity retention.


2020 ◽  
Vol 466 ◽  
pp. 228315 ◽  
Author(s):  
W. Blake Hawley ◽  
Anand Parejiya ◽  
Yaocai Bai ◽  
Harry M. Meyer ◽  
David L. Wood ◽  
...  

2018 ◽  
Vol 165 (11) ◽  
pp. A2849-A2858 ◽  
Author(s):  
Jianping Huang ◽  
Lisa M. Housel ◽  
Calvin D. Quilty ◽  
Alexander B. Brady ◽  
Paul F. Smith ◽  
...  

2020 ◽  
Vol 167 (2) ◽  
pp. 020513 ◽  
Author(s):  
Ritu Sahore ◽  
Daniel C. O’Hanlon ◽  
Adam Tornheim ◽  
Chang-Wook Lee ◽  
Juan C. Garcia ◽  
...  

2015 ◽  
Vol 3 (40) ◽  
pp. 20103-20107 ◽  
Author(s):  
Yu-Feng Deng ◽  
Shi-Xi Zhao ◽  
Peng-Yuan Zhai ◽  
Guozhong Cao ◽  
Ce-Wen Nan

Li1+xNi0.5−xMn1.5O4, madeviaa novel one-step co-precipitation route, undergoes a disordered-to-ordered phase change. Transition metal ions in tetrahedral sites could influence the performance more than the cationic ordering in octahedral sites does.


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