In Situ Construction of COF-Based Paper Serving as a Plasmonic Substrate for Enhanced PSI-MS Detection of Polycyclic Aromatic Hydrocarbons

Author(s):  
Guang-Lu Zhang ◽  
Minmin Zhang ◽  
Qian Shi ◽  
Zhongyao Jiang ◽  
Lili Tong ◽  
...  
2019 ◽  
Author(s):  
Thomas Delouche ◽  
Antoine Vacher ◽  
Elsa Caytan ◽  
Thierry Roisnel ◽  
Boris Le Guennic ◽  
...  

In this communication, we report the straightforward<br>synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach.<br>Finally, (spectro)-electrochemical studies prove that these<br>compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical.


2009 ◽  
Vol 52 (5) ◽  
pp. 492-500 ◽  
Author(s):  
Benjamín Solsona ◽  
Tomás García ◽  
Ramón Murillo ◽  
Ana M. Mastral ◽  
Edwin Ntainjua Ndifor ◽  
...  

Author(s):  
Emanuela Frapiccini ◽  
Evgeniya Prokofyeva ◽  
Antonina Bondarenko ◽  
Maria Letizia Ruello ◽  
Mauro Marini

The present study describes the activities performed to test a new method for measuring the mobility of polycyclic aromatic hydrocarbons (PAHs) in the solid phase of sediments within the context of environmental pollution risk assessment. The method is based on the design of a new configuration (new materials) of the commercial passive sampler Chemcatcher as probe for predicting the bioavailability of persistent organic pollutants in marine sediments (or in water saturated soils).


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