Stabilizing Li10SnP2S12/Li Interface via an in Situ Formed Solid Electrolyte Interphase Layer

2018 ◽  
Vol 10 (30) ◽  
pp. 25473-25482 ◽  
Author(s):  
Bizhu Zheng ◽  
Jianping Zhu ◽  
Hongchun Wang ◽  
Min Feng ◽  
Ediga Umeshbabu ◽  
...  
2019 ◽  
Vol 30 (7) ◽  
pp. 1907717 ◽  
Author(s):  
Dongdong Chen ◽  
Sheng Huang ◽  
Lei Zhong ◽  
Shuanjin Wang ◽  
Min Xiao ◽  
...  

2017 ◽  
Vol 29 (11) ◽  
pp. 4728-4737 ◽  
Author(s):  
Manjula I. Nandasiri ◽  
Luis E. Camacho-Forero ◽  
Ashleigh M. Schwarz ◽  
Vaithiyalingam Shutthanandan ◽  
Suntharampillai Thevuthasan ◽  
...  

2018 ◽  
Vol 10 (21) ◽  
pp. 17985-17993 ◽  
Author(s):  
Seong-Jin Park ◽  
Jang-Yeon Hwang ◽  
Chong S. Yoon ◽  
Hun-Gi Jung ◽  
Yang-Kook Sun

2019 ◽  
Vol 11 (46) ◽  
pp. 43200-43205 ◽  
Author(s):  
Na Wu ◽  
Ya-Ru Shi ◽  
Ting Jia ◽  
Xue-Ning Du ◽  
Ya-Xia Yin ◽  
...  

Author(s):  
G. Ramos-Sanchez ◽  
F. A. Soto ◽  
J. M. Martinez de la Hoz ◽  
Z. Liu ◽  
P. P. Mukherjee ◽  
...  

Understanding interfacial phenomena such as ion and electron transport at dynamic interfaces is crucial for revolutionizing the development of materials and devices for energy-related applications. Moreover, advances in this field would enhance the progress of related electrochemical interfacial problems in biology, medicine, electronics, and photonics, among others. Although significant progress is taking place through in situ experimentation, modeling has emerged as the ideal complement to investigate details at the electronic and atomistic levels, which are more difficult or impossible to be captured with current experimental techniques. Among the most important interfacial phenomena, side reactions occurring at the surface of the negative electrodes of Li-ion batteries, due to the electrochemical instability of the electrolyte, result in the formation of a solid-electrolyte interphase layer (SEI). In this work, we briefly review the main mechanisms associated with SEI reduction reactions of aprotic organic solvents studied by quantum mechanical methods. We then report the results of a Kinetic Monte Carlo method to understand the initial stages of SEI growth.


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