Abstract. Reconstruction of the oxidative capacity of the atmosphere is of great importance to understanding climate change, because of its key role in determining the life times of trace gases. Triple oxygen isotopic compositions (Δ17O = δ17O − 0.52 × δ18O) of atmospheric sulfate (SO42−) and nitrate (NO3−) in the Antarctic ice cores have shown potential as stable proxies, because they reflect the oxidation chemistry involved in their formation processes. However, observations of Δ17O values of SO42−, NO3− and ozone in the present-day Antarctic atmosphere are very limited, and their complex chemistry is not fully understood in this region. We present the first simultaneous measurement of Δ17O values of atmospheric sulfate, nitrate, and ozone collected at Dumont d'Urville station (66°40' S, 140°01' E) throughout 2011. Δ17O values of sulfate and nitrate exhibited seasonal variation characterized by summer minima and winter maxima, within the ranges of 0.9–3.4 ‰ and 23.0–41.9 ‰, respectively. In contrast, Δ17O values of ozone showed no significant seasonal variation, with values of 26 ± 1 ‰ through the year. These contrasting seasonal trends suggest that Δ17O(O3) is not the major factor determining seasonal changes in Δ17O(SO42−) and Δ17O(NO3−) values. The summer/winter trends for Δ17O(SO42−) and Δ17O(NO3−) values are caused by sunlight-driven changes in O3/ROX ratios, which decrease in summer through ozone destruction and photo-oxidants production, resulting in co-variation between ozone mixing ratios and Δ17O(SO42−) and Δ17O(NO3−) values. However, despite similar ranges of ozone mixing ratios in spring (September to November) and fall (March to May), Δ17O(SO42−) values observed in spring were lower than in fall. The relatively low sensitivity of Δ17O(SO42−) values to the ozone mixing ratio in spring is possibly explained by (i) lower O3/ROX ratios caused by NOX emission from snowpack and/or (ii) SO2 oxidation by hypohalous acids (HOX = HOCl + HOBr) in the aqueous phase.