scholarly journals Halide Mixing Inhibits Exciton Transport in Two-dimensional Perovskites Despite Phase Purity

2021 ◽  
pp. 358-365
Author(s):  
Michael Seitz ◽  
Marc Meléndez ◽  
Peyton York ◽  
Daniel A. Kurtz ◽  
Alvaro J. Magdaleno ◽  
...  
2021 ◽  
Author(s):  
Ferry Prins ◽  
Michael Seitz ◽  
Marc Melendez ◽  
Peyton York ◽  
Daniel Kurtz ◽  
...  

2020 ◽  
Author(s):  
Alvaro J Magdaleno ◽  
Michael Seitz ◽  
Michel Frising ◽  
Ana Herranz de la Cruz ◽  
Antonio I. Fernández-Domínguez ◽  
...  

We present transient microscopy measurements of interlayer energy transport in (PEA)<sub>2</sub>PbI<sub>4</sub> perovskite. We find efficient interlayer exciton transport (0.06 cm<sup>2</sup>/s), which translates into a diffusion length that exceeds 100 nm and a sub-ps timescale for energy transfer. While still slower than in-plane exciton transport (0.2 cm<sup>2</sup>/s), our results show that excitonic energy transport is considerably less anisotropic than charge-carrier transport for 2D perovskites.


2020 ◽  
Author(s):  
Alvaro J Magdaleno ◽  
Michael Seitz ◽  
Michel Frising ◽  
Ana Herranz de la Cruz ◽  
Antonio I. Fernández-Domínguez ◽  
...  

We present transient microscopy measurements of interlayer energy transport in (PEA)<sub>2</sub>PbI<sub>4</sub> perovskite. We find efficient interlayer exciton transport (0.06 cm<sup>2</sup>/s), which translates into a diffusion length that exceeds 100 nm and a sub-ps timescale for energy transfer. While still slower than in-plane exciton transport (0.2 cm<sup>2</sup>/s), our results show that excitonic energy transport is considerably less anisotropic than charge-carrier transport for 2D perovskites.


2020 ◽  
Vol 6 (51) ◽  
pp. eabb4823
Author(s):  
Yiling Yu ◽  
Yifei Yu ◽  
Guoqing Li ◽  
Alexander A. Puretzky ◽  
David B. Geohegan ◽  
...  

Two-dimensional (2D) semiconductors bear great promise for application in optoelectronic devices, but the low diffusivity of excitons stands as a notable challenge for device development. Here, we demonstrate that the diffusivity of excitons in monolayer MoS2 can be improved from 1.5 ± 0.5 to 22.5 ± 2.5 square centimeters per second with the presence of trapped charges. This is manifested by a spatial expansion of photoluminescence when the incident power reaches a threshold value to enable the onset of exciton Mott transition. The trapped charges are estimated to be in a scale of 1010 per square centimeter and do not affect the emission features and recombination dynamics of the excitons. The result indicates that trapped charges provide an attractive strategy to screen exciton scattering with phonons and impurities/defects. Pointing towards a new pathway to control exciton transport and many-body interactions in 2D semiconductors.


Author(s):  
Julian Lüttig ◽  
Pavel Malý ◽  
Arthur Turkin ◽  
Katja Mayershofer ◽  
Simon Büttner ◽  
...  

2021 ◽  
Author(s):  
Chloe L. Tolbert ◽  
Caleb Hill

Two-dimensional semiconductors (2DSCs) are attractive for a variety of optoelectronic and catalytic applications due to their ability to be fabricated as wide-area, monolayer-thick films and their unique optical and electronic...


1988 ◽  
Vol 53 (20) ◽  
pp. 1937-1939 ◽  
Author(s):  
H. Hillmer ◽  
S. Hansmann ◽  
A. Forchel ◽  
M. Morohashi ◽  
E. Lopez ◽  
...  

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