Titanium Dioxide/Phosphorous-Functionalized Cellulose Acetate Nanocomposite Membranes for DMFC Applications: Enhancing Properties and Performance

In this study, cellulose acetate/polyethylene glycol (CA/PEG) membrane with composition 80/20 was prepared by phase inversion method. Titanium dioxide with different number has been added by using surface coating. Hydrophilicity, morphology, flux permeate and salt rejection of membranes has been studied. The hydrophilicity is determined by Fourier-Transformed Infra-Red (FTIR) spectra and contact angle analysis. Surface and fractured morphology are identified by using Scanning Electron Microscopy (SEM). The experiment results show that hydrophilicity of CA/PEG membrane increases with the addition and the increasing of TiO2 contents. However, with further increasing of TiO2, hydrophilicity of CPT membrane decreases. The optimum membrane is CA/PEG/TiO2 80/20/1,25 g/L solvent (CPT 3) with flux permeate of 111,82 L.m-2h-1 and salt rejection of 48,30%.

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Biodegradable blend membranes of poly (butylene succinate)/cellulose acetate/dextran: Preparation, characterization and performance

Carbohydrate Polymers ◽

10.1016/j.carbpol.2017.06.010 ◽

2017 ◽

Vol 173 ◽

pp. 497-507 ◽

Cited By ~ 15

Author(s):

Ali Hoseinzadeh Bahremand ◽

Seyed Mahmoud Mousavi ◽

Ali Ahmadpour ◽

Mostafa Taherian

Keyword(s):

Cellulose Acetate ◽

Butylene Succinate ◽

Blend Membranes ◽

And Performance

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Preparation and Performance Evaluation of Duotone 3D-Printed Polyetheretherketone as Oral Prosthetic Materials: A Proof-of-Concept Study

Polymers ◽

10.3390/polym13121949 ◽

2021 ◽

Vol 13 (12) ◽

pp. 1949

Author(s):

Ling Ding ◽

Wei Lu ◽

Jiaqi Zhang ◽

Chuncheng Yang ◽

Guofeng Wu

Keyword(s):

Titanium Dioxide ◽

Performance Evaluation ◽

Mechanical Performance ◽

Mechanical Tests ◽

Flexural Properties ◽

Proof Of Concept ◽

Tooth Color ◽

Dental Application ◽

3D Printed ◽

And Performance

Literature has reported the successful use of 3D printed polyetheretherketone (PEEK) to fabricate human body implants and oral prostheses. However, the current 3D printed PEEK (brown color) cannot mimic the vivid color of oral tissues and thus cannot meet the esthetical need for dental application. Therefore, titanium dioxide (TiO2) and ferric oxide (Fe2O3) were incorporated into PEEK to prepare a series of tooth-color and gingival-color PEEK composites in this study. Through color measurements and mechanical tests, the color value and mechanical performance of the 3D printed PEEK composites were evaluated. In addition, duotone PEEK specimens were printed by a double nozzle with an interface between tooth-color and gingival-color parts. The mechanical performance of duotone PEEK with two different interfaces (horizontal and vertical) was investigated. With the addition of TiO2 and Fe2O3, the colors of 3D printed PEEK composites become closer to that of dental shade guides. 3D printed PEEK composites generally demonstrated superior tensile and flexural properties and hence have great potential in the dental application. In addition, duotone 3D printed PEEK with a horizontal interfacial orientation presented better mechanical performance than that with a vertical one.

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