The object of research is plasmonic properties copper of monosulfide nanoparticles. One of the most problematic areas is that there is still no unambiguous answer to which main copper monosulfide nanoparticles parameters have a decisive effect on their resonance absorption, scattering or electric field enhancement. It is necessary to study the plasmonic properties of copper monosulfide nanoparticles depending on their main parameter, namely the dielectric constant. The principle of dipole equivalence and Mee-Gans theory for the modeling of the optical nanoparticle characteristics is used. It is found that dielectric constant is a crucial parameter determining the resulting optical response of such nanoparticles. The surrounding medium refractive index affects the position and magnitude of the nanoparticles maximum plasmonic absorption. The nonspherical nanoparticles are characterized by two plasmon peaks corresponding to transverse and longitudinal localized surface plasmon resonance if the ratio between the axes is higher than 1.5. The ellipsoidal nanoparticles exhibit higher sensitivity to changes in the refractive index of the surrounding medium in comparison to the spherical ones. The obtained research results are primarily the basis for further comprehensive research of plasmonic copper monosulfide nanoparticles for their specialized applications. Second, knowledge of the influence of the nanoparticle dielectric constant on their resulting spectral characteristics allow tuning of the localized surface plasmon resonance peak position in a wide wavelength range, from 500 to 1200 nm, using the nanoparticle synthesis technique. Thus, the material under study is promising for sensor applications in a wide spectral range.
Study of plasmonic properties of copper monosulfide nanoparticles depending on their dielectric constant
