Synthesis and Electrochemical Reaction of a Pitch Carbon-Coated Zinc Vanadium Oxide Anode with Excellent Electrochemical Performance for Rechargeable Lithium Batteries

2020 ◽  
Vol 8 (4) ◽  
pp. 1908-1915 ◽  
Author(s):  
Jae Hyeon Jo ◽  
Ji Ung Choi ◽  
Hee Jae Kim ◽  
Hitoshi Yashiro ◽  
Seung-Taek Myung
2014 ◽  
Vol 989-994 ◽  
pp. 316-319 ◽  
Author(s):  
Jing Zhu ◽  
Yong Guang Liu ◽  
Qing Qing Tian ◽  
Ling Wang ◽  
Ji Lin Cao

Li0.95Na0.05Ti2(PO4)3/C nanocomposite was prepared by sol-gel method.The structure and morphology of the samples were characterized by XRD, SEM which showed the particles had typical NASICON structure and diameter range from 400~500nm. The electrochemical performance were tested by cyclic voltammetry and galvanostatic charge–discharge. Results show Li0.95Na0.05Ti2(PO4)3/C nanocomposite exhibitsmuch better electrochemical performance than bare Li0.95Na0.05Ti2(PO4)3.


2016 ◽  
Vol 09 (01) ◽  
pp. 1650004 ◽  
Author(s):  
Jiangfeng Ni ◽  
Jiaxing Jiang ◽  
S. V. Savilov ◽  
S. M. Aldoshin

Nanostructured LiFePO4 is appealing cathode material for rechargeable lithium batteries. Herein, however, we report the intriguing anode properties of carbon coated LiFePO4 nanocrystals. In the potential range of 0–3.0 V, the LiFePO4 nanocrystal electrodes afford high reversible capacity of 373 mAh[Formula: see text]g[Formula: see text] at a current rate of 0.05 A[Formula: see text]g[Formula: see text] and retains 239 mAh[Formula: see text]g[Formula: see text] at a much higher rate of 1.25 A[Formula: see text]g[Formula: see text]. In addition, it is capable of sustaining 1000 cycles at 1.25 A[Formula: see text]g[Formula: see text] without any capacity fading. Such superior properties indicate that nanostructured LiFePO4 could also be promising anode for rechargeable battery applications.


2018 ◽  
Vol 47 (8) ◽  
pp. 2711-2718 ◽  
Author(s):  
Zhaohui Meng ◽  
Song Wang ◽  
Lijuan Wang ◽  
Hongjiang Hou

LZTO@C–N with an excellent electrochemical performance has been synthesized using NTA as C and N sources, as well as a chelating agent.


RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 37923-37928 ◽  
Author(s):  
Min-Young Cho ◽  
Seung-Beom Yoon ◽  
Kwang-Bum Kim ◽  
Dae Soo Jung ◽  
Kwang Chul Roh

Thin carbon-coated single Fe3O4 nanocomposite were synthesized by a solvothermal process using dodecylamine. The composite structure can accommodate the large volume change of Fe3O4 and thus enabled excellent electrochemical performance.


1997 ◽  
Vol 496 ◽  
Author(s):  
Ji-Guang Zhang ◽  
Ping Liu ◽  
C. Edwin Tracy ◽  
David K. Benson ◽  
John A. Turner

ABSTRACTPlasma Enhanced Chemical Vapor Deposition (PECVD) was used to prepare vanadium oxide thin films as cathodes for rechargeable lithium batteries. The reactants consisted of a high vapor pressure liquid source of vanadium (VOCl3) and hydrogen and oxygen gas. Deposition parameters such as the flow rates of H2, O2 and VOCl3, the substrate temperature and the Rf power were optimized, and high deposition rate of 11 Å/s was obtained. Vanadium oxide films with high discharge capacities of up to 408 mAh/g were prepared. The films also showed a superior cycling stability between 4 and 1.5 V at a C/0.2 rate for more than 4400 cycles. The films were amorphous up to a deposition temperature of 300°C, however, deposition on to substrates with textured surfaces facilitated the formation of crystalline films. We demonstrate that both the vanadium oxide material and the PECVD deposition method are very attractive for constructing thin-film rechargeable lithium batteries with high capacity and long-term cyclic stability.


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