Modulation of Polymer Refractive Indices with Diamond Nanoparticles for Metal-Free Multilayer Film Mirrors

2012 ◽  
Vol 4 (8) ◽  
pp. 3769-3772 ◽  
Author(s):  
Tomonari Ogata ◽  
Ryohei Yagi ◽  
Nozomi Nakamura ◽  
Yutaka Kuwahara ◽  
Seiji Kurihara
ACS Omega ◽  
2018 ◽  
Vol 3 (11) ◽  
pp. 16099-16104 ◽  
Author(s):  
Laia Ginés ◽  
Soumen Mandal ◽  
David John Morgan ◽  
Ryan Lewis ◽  
Philip R. Davies ◽  
...  

Author(s):  
Mickey E. Gunter ◽  
F. Donald Bloss

A single, reasonably homogeneous, nonopaque 30-to-300 μm crystal, mounted on a spindle stage and studied by immersion methods under a polarizing microscope, yields optical data frequently sufficient to identify and characterize a substance unequivocally. The data obtainable include (1) the orientation of the crystal's principal vibration axes and (2) its principal refractive indices, to within 0.0002 if desired, for light vibrating along these principal vibration axes. Spindle stages tend to be simple and relatively inexpensive, some costing less than $50. They permit rotation of the crystal about a single axis which is parallel to the microscope stage. This spindle or S-axis is thus perpendicular to the M-axis, namely the microscope stage's axis of rotation.A spindle stage excels when studying anisotropic crystals. It orients uniaxial crystals within minutes and biaxial crystals almost as quickly so that their principal refractive indices - ɛ and ω (uniaxial); α, β and γ (biaxial) - can be determined without significant error from crystal misorientation.


Author(s):  
George C. Ruben

The formation of shadows behind small particles has been thought to be a geometric process (GP) where the metal cap build up on the particle creates a shadow width the same size as or larger than the particle. This GP cannot explain why gold particle shadow widths are generally larger than the gold particle and may have no appreciable metal cap build up (fig. 1). Ruben and Telford have suggested that particle shadow widths are formed by the width dependent deflection of shadow metal (SM) lateral to and infront of the particle. The trajectory of the deflected SM is determined by the incoming shadow angle (45°). Since there can be up to 1.4 times (at 45°) more SM directly striking the particle than the film surface, a ridge of metal nuclei lateral to and infront of the particle can be formed. This ridge in turn can prevent some SM from directly landing in the metal free shadow area. However, the SM that does land in the shadow area (not blocked by the particle or its ridge) does not stick and apparently surface migrates into the SM film behind the particle.


Author(s):  
Matthew R. Libera ◽  
Martin Chen

Phase-change erasable optical storage is based on the ability to switch a micron-sized region of a thin film between the crystalline and amorphous states using a diffraction-limited laser as a heat source. A bit of information can be represented as an amorphous spot on a crystalline background, and the two states can be optically identified by their different reflectivities. In a typical multilayer thin-film structure the active (storage) layer is sandwiched between one or more dielectric layers. The dielectric layers provide physical containment and act as a heat sink. A viable phase-change medium must be able to quench to the glassy phase after melting, and this requires proper tailoring of the thermal properties of the multilayer film. The present research studies one particular multilayer structure and shows the effect of an additional aluminum layer on the glass-forming ability.


Author(s):  
Walter C. McCrone

An excellent chapter on this subject by V.D. Fréchette appeared in a book edited by L.L. Hench and R.W. Gould in 1971 (1). That chapter with the references cited there provides a very complete coverage of the subject. I will add a more complete coverage of an important polarized light microscope (PLM) technique developed more recently (2). Dispersion staining is based on refractive index and its variation with wavelength (dispersion of index). A particle of, say almandite, a garnet, has refractive indices of nF = 1.789 nm, nD = 1.780 nm and nC = 1.775 nm. A Cargille refractive index liquid having nD = 1.780 nm will have nF = 1.810 and nC = 1.768 nm. Almandite grains will disappear in that liquid when observed with a beam of 589 nm light (D-line), but it will have a lower refractive index than that liquid with 486 nm light (F-line), and a higher index than that liquid with 656 nm light (C-line).


Nanoscale ◽  
2020 ◽  
Vol 12 (15) ◽  
pp. 8065-8094 ◽  
Author(s):  
Xudong Wen ◽  
Jingqi Guan

Different kinds of electrocatalysts used in NRR electrocatalysis (including single atom catalysts, metal oxide catalysts, nanocomposite catalysts, and metal free catalysts) are introduced.


2020 ◽  
Vol 7 (21) ◽  
pp. 3515-3520
Author(s):  
Wubing Yao ◽  
Jiali Wang ◽  
Aiguo Zhong ◽  
Shiliang Wang ◽  
Yinlin Shao

The selective catalytic reduction of amides to value-added amine products is a desirable but challenging transformation.


Author(s):  
Fengqian Zhao ◽  
Xiao-Feng Wu

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.


1983 ◽  
Vol 44 (12) ◽  
pp. 349-359
Author(s):  
Wataru Kinase ◽  
Tadataka Morishita ◽  
Yutaka Hiyama ◽  
Tomoo Maeda
Keyword(s):  

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