The Anodic Oxidation of Carbon Monoxide and Formic Acid on Platinum Covered with Sulfur

Author(s):  
H. BINDER ◽  
A. KÖHLING ◽  
G. SANDSTEDE
2011 ◽  
Vol 16 (2) ◽  
pp. 587-595 ◽  
Author(s):  
Maja D. Obradović ◽  
Amalija V. Tripković ◽  
Snežana Lj. Gojković

1984 ◽  
Vol 37 (12) ◽  
pp. 2415 ◽  
Author(s):  
TR Farrugia ◽  
RA Fredlein

The anodic oxidation of carbon monoxide on gold was studied in the oxide-free potential region, linear sweep voltammetry being used to minimize electrode poisoning. Only when pco < c. 0.3 atm or when the reaction was inhibited by impurities were the plots of i against square root of scan rate linear. In other cases, i attained constant values at high scan rates; this is interpreted, together with other evidence, as due to the adsorption of CO prior to the start of the scan. Good Tafel plots were obtained under conditions where i was independent of scan rate, and the kinetic parameters are shown to be consistent with the Gilman reactant-pair mechanism. In the potential region of oxide formation on gold, the steady-state oxidation of CO proceeded with the formation of colloidal gold. The mechanism in this potential region was not investigated.


2021 ◽  
Vol 46 (17) ◽  
pp. 10239-10246
Author(s):  
Mengyin Liao ◽  
Weiping Li ◽  
Jiaxi Peng ◽  
Fan Zhang ◽  
Wenyuan Xu ◽  
...  

Author(s):  
Thulani M. Nyathi ◽  
Mohamed I. Fadlalla ◽  
Nico Fischer ◽  
Andrew P.E. York ◽  
Ezra J. Olivier ◽  
...  

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