Solid State Isotope Exchange with Spillover Hydrogen in Organic Compounds

2010 ◽  
Vol 110 (9) ◽  
pp. 5425-5446 ◽  
Author(s):  
Yu. A. Zolotarev ◽  
A. K. Dadayan ◽  
Yu. A. Borisov ◽  
V. S. Kozik
Keyword(s):  
Solid State ◽  
Organic Compounds ◽  
Isotope Exchange ◽  
Spillover Hydrogen

ChemInform Abstract: Solid State Isotope Exchange with Spillover Hydrogen in Organic Compounds

ChemInform ◽  
2010 ◽  
Vol 41 (51) ◽  
pp. no-no
Author(s):  
Yu. A. Zolotarev ◽  
A. K. Dadayan ◽  
Yu. A. Borisov ◽  
V. S. Kozik
Keyword(s):  
Solid State ◽  
Organic Compounds ◽  
Isotope Exchange ◽  
Spillover Hydrogen

New Development in the Solid-State Isotope Exchange with Spillover Hydrogen in Organic Compounds

2013 ◽  
Vol 117 (33) ◽  
pp. 16878-16884 ◽  
Author(s):  
Yurii A. Zolotarev ◽  
Alexander K. Dadayan ◽  
Yurii A. Borisov ◽  
Valery S. Kozik ◽  
Igor V. Nazimov ◽  
...  
Keyword(s):  
Solid State ◽  
Organic Compounds ◽  
Isotope Exchange ◽  
New Development ◽  
Spillover Hydrogen

scholarly journals Solid state catalytic hydrogen exchange for deuterium in cycloprolylglycine

2019 ◽  
Vol 484 (3) ◽  
pp. 307-311
Author(s):  
A. K. Dadayan ◽  
Yu. A. Borisov ◽  
E. V. Bocharov ◽  
Yu. A. Zolotarev ◽  
I. Yu. Nagaev ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Solid State ◽  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Density Functional ◽  
Hydrogen Exchange ◽  
Functional Theory ◽  
Catalytic Hydrogen ◽  
Spillover Hydrogen ◽  
High Stereoselectivity

The reaction of spillover hydrogen (SH) with cyclopropylglycine (cPG) in high-temperature solid-state catalytic hydrogen isotope exchange (HTCIE) has been studied experimentally and using density functional theory (DFT). NMR spectroscopy and mass spectrometry have shown a high regioselectivity and stereoselectivity for the reaction of spillover hydrogen with cPG fragments. The Gly fragment has been shown to be the most reactive in HTCIE, for which high stereoselectivity of substitution of hydrogen by deuterium has been demonstrated.

The effect of three-dimensional structure on the solid state isotope exchange of hydrogen in polypeptides with spillover hydrogen

2003 ◽  
Vol 31 (6) ◽  
pp. 453-463 ◽  
Author(s):  
Yu.A. Zolotarev ◽  
A.K. Dadayan ◽  
Yu.A. Borisov ◽  
E.M. Dorokhova ◽  
V.S. Kozik ◽  
...  
Keyword(s):  
Solid State ◽  
Isotope Exchange ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Three Dimensional Structure ◽  
Spillover Hydrogen

Solid state chemical ionization for characterization of organic compounds by laser mass spectrometry

Talanta ◽  
1989 ◽  
Vol 36 (1-2) ◽  
pp. 117-124 ◽  
Author(s):  
Kesagapillai Balasanmugam ◽  
Somayajula Kasi Viswanadham ◽  
David M. Hercules
Keyword(s):  
Mass Spectrometry ◽  
Solid State ◽  
Organic Compounds ◽  
Chemical Ionization ◽  
Laser Mass Spectrometry ◽  
State Chemical

A double-frequency solid-state laser on organic compounds

2009 ◽  
Vol 52 (7) ◽  
pp. 655-660 ◽  
Author(s):  
T. N. Kopylova ◽  
G. V. Maier ◽  
E. N. Telminov ◽  
V. A. Svetlichnyi ◽  
K. M. Degtyarenko
Keyword(s):  
Solid State ◽  
Organic Compounds ◽  
Solid State Laser ◽  
State Laser ◽  
Double Frequency

scholarly journals Molecular-level electrochemical doping for fine discrimination of volatile organic compounds in organic chemiresistors

2020 ◽  
Vol 8 (33) ◽  
pp. 16884-16891 ◽  
Author(s):  
Sooncheol Kwon ◽  
Yusin Pak ◽  
Bongseong Kim ◽  
Byoungwook Park ◽  
Jehan Kim ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Organic Compounds ◽  
Room Temperature ◽  
Molecular Level ◽  
Interfacial Area ◽  
Volatile Organic ◽  
Molecular Scale ◽  
Ppm Level ◽  
State Ionic

A blend of π-CPs and a solid-state ionic liquid provides an enlarged interfacial area at the molecular scale, thereby enabling two-terminal organic chemiresistors (TOCs) with fine discriminatory abilities for sub-ppm-level VOCs at room temperature.

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