Charge transfer in Lewis acid-base reactions: A MO study of the H3+ system

1989 ◽  
Vol 66 (11) ◽  
pp. 898
Author(s):  
G. M. Fernandez ◽  
J. A. Sordo ◽  
T. L. Sordo
Keyword(s):  
Charge Transfer ◽  
Lewis Acid ◽  
Acid Base

Origins of Lewis acid accelerations in nickel catalysed C–H, C–C and C–O bond cleavages

2021 ◽  
Author(s):  
Han Gao ◽  
Lingfei Hu ◽  
Yanlei Hu ◽  
Xiangying Lv ◽  
Yanbo Wu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Lewis Acid ◽  
Transition Metal Catalysis ◽  
Current Understanding ◽  
Acid Base ◽  
Metal Catalysis

The current understanding of Lewis acid effects in transition metal catalysis is generally based on the enhanced charge transfer from metal to substrate due to the formation of Lewis acid-base...

Charge Transfer via the Dative N−B Bond and Dihydrogen Contacts. Experimental and Theoretical Electron Density Studies of Small Lewis Acid−Base Adducts

2010 ◽  
Vol 114 (37) ◽  
pp. 10185-10196 ◽  
Author(s):  
Stefan Mebs ◽  
Simon Grabowsky ◽  
Diana Förster ◽  
Rainer Kickbusch ◽  
Monika Hartl ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electron Density ◽  
Lewis Acid ◽  
Acid Base

scholarly journals Rationalizing Energy Level Alignment by Characterizing Lewis Acid/Base and Ionic Interactions at Printable Semiconductor/Ionic Liquid Interfaces

2022 ◽  
Author(s):  
Linze Du Hill ◽  
Michel De Keersmaecker ◽  
Adam E Colbert ◽  
Joshua W Hill ◽  
Diogenes Placencia ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Charge Transfer ◽  
Energy Level ◽  
Vapor Pressure ◽  
Electric Field ◽  
Lewis Acid ◽  
Ionic Interactions ◽  
Liquid Interfaces ◽  
Acid Base ◽  
Field Distributions

Charge transfer and energy conversion processes at semiconductor/electrolyte interfaces are controlled by local electric field distributions, which can be especially challenging to measure. Herein we leverage the low vapor pressure...

Pyrazinoindole-Based Lewis-Acid/Base Assembly: Intriguing Intramolecular Charge-Transfer Switching through the Dual-Sensing of Fluoride and Acid

2019 ◽  
Vol 84 (7) ◽  
pp. 3843-3852 ◽  
Author(s):  
Yonghyeon Baek ◽  
Youngjae Kwon ◽  
Chanyoung Maeng ◽  
Ji Hye Lee ◽  
Hyonseok Hwang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Lewis Acid ◽  
Intramolecular Charge Transfer ◽  
Acid Base ◽  
Dual Sensing

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

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